The Nature of Proteins

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The Nature of Proteins

Proteins consist of carbon, hydrogen, oxygen and also nitrogen.

Proteins are macromolecules. They are constructed from one or more

unbranched chains of amino acids; that is, they are polymers (

Compound whose molecule consists of many repeated units linked

together). A typical protein contains 200-300 amino acids but some are

much smaller (the smallest are often called peptides) and some much

larger.

Amino Acids

Amino acids are the building blocks (monomers) of proteins. 20

different amino acids are used to synthesize proteins. The shape and

other properties of each protein is dictated by the precise sequence

of amino acids in it.

Each amino acid consists of an alpha carbon atom to which is attached

a hydrogen atom

an amino group (hence "amino" acid)

A carboxyl group (-COOH). This gives up a proton and is thus an acid

(hence amino "acid") [IMAGE]

One of 20 different "R" groups. It is the structure of the R group

that determines which of the 20 it is and its special properties. The

amino acid shown here is Alkaline.

Amino acids contain an amino or NH2 group and a carboxyl (acid) or

COOH group.

The ionization of water

Amino-acids at physiological pH values predominate at an ionization

state where the alpha-amino group is positively charged (a cation)

whereas the carboxyl group has a negative charge (an anion). This is

called a zwitterion.

The Peptide Bond

The amino acids are linked linearly through peptide bonds. These bonds

are formed via a dehydration synthesis reaction between the carboxy

group of the first amino acid with the amino group of the second amino

acid. Water is given of in this reaction therefore it makes it a

condensation reaction.

If you would wish to reverse this reaction you would use a hydrolysis

reaction. To do this you would add water.

[IMAGE]This is an example of a condensation reaction which results in

the formation of peptide bonds.

When two amino acids are combined this forms a dipeptide.

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