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Heat of combustion of different alcohols
Heat of combustion of different alcohols
Heat of combustion of different alcohols
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The data collected through the experiment and the graph indicate that there is a positive relationship between the number of carbons in a carbon chain of an alcohol and the enthalpy of combustion of the alcohol. Meaning as the number of carbon atoms in an alcohol chain increases, its enthalpy change of combustion also increases. The average enthalpy of combustion of all alcohol in Table 3 supports the conclusion. From the table, one can notice that Ethanol’s enthalpy of combustion is 319 higher/lower (need to show the calculation?) than methanol, and ethanol has one more carbon than methanol. This correlation can also be supported by the graph. The upward trend in the bar graph shows the relationship between the two variables. The increase in enthalpy from methanol to …show more content…
Same as the factor above, this leads to an inaccurate measurement of the amount of enthalpy of combustion for the alcohol. This error is hard to eliminate, as we cannot accurately measure how much energy is taken away from the surroundings and how much of heat energy was actually absorbed by water. Thirdly, during the experiment, a yellow flame was obtained. This indicates that there is incomplete combustion of the alcohols. Instead of producing carbon dioxide, carbon monoxide is formed. Therefore, this incomplete combustion results in low standard enthalpy of combustion values as the reaction was not complete. Lastly, during the experiment, tap water was used to measure the change in temperature. However, tap water contains several unknown ions and minerals and every time when the conical flask was refilled with water, the concentration of those ions and minerals may vary. Furthermore, when calculating the heat energy, we used the specific heat capacity used of the water; however, the unknown minerals may affect the specific heat capacity of the
Thermodynamics is essentially how heat energy transfers from one substance to another. In “Joe Science vs. the Water Heater,” the temperature of water in a water heater must be found without measuring the water directly from the water heater. This problem was translated to the lab by providing heated water, fish bowl thermometers, styrofoam cups, and all other instruments found in the lab. The thermometer only reaches 45 degrees celsius; therefore, thermodynamic equations need to be applied in order to find the original temperature of the hot water. We also had access to deionized water that was approximately room temperature.
Lab 4: Energy Conservation: Hot Stuff!! The purpose of this experiment is to try to find the original temperature of the hot water in the heater using the 60 degrees C thermometer. Use your 60°C thermometer, and any materials available in your laboratory, to determine the temperature of the water in the coffee pot. During this experiment we calculated the original temperature of a heater after it had been cooled down, and we did this by measuring hot, cold, and warm water, with a thermometer that had tape covering 60 degrees and up.
The purpose of the lab is to understand how to calculate the calorimeter constant by using a calorimeter. This allows us to analyze the heat reaction of different substances. Calorimetry is a word that comes from both Latin and Greek. The prefix “Calor” in Latin signifies heat and the suffix “metry” in Greek means measuring. Therefore the word itself translates to measuring heat. Joseph Black, was the first scientist to recognize the difference between heat and temperature. Energy is always present in chemical and physical changes. The change of energy that occurs when there is a chemical change at constant pressure is called enthalpy. Enthalpy changes , as well as physical and chemical changes, can be measured by a calorimeter. The energy that is released or absorbed by the reaction can be either absorbed or released by the insulating walls of the instrument.
Stauffer, Nancy. ”MIT ethanol analysis confirms benefits of biofuels.” Laboratory for Energy and the Environment. January 2007.
An error that occurred in the experiment was during the ceric nitrate test because solution 4 should have produced a color change. During a base hydrolysis of aspartame, aspartic acid, phenylalanine and methanol are produced, therefore the ceric nitrate test should have been a positive for alcohol. A reason that this could have shown a negative result is because methanol is a volatile substance and it could have evaporated out, which would have caused a negative ceric nitrate test
This is expressed as Δ +ve (delta positive). If the total energy put in is less than the energy created, then the substance warms up (it is exothermic). This is expressed as Δ -ve (delta negative). I will investigate eight different alcohols using an alcohol or spirit burner, to measure the energy change during burning by measuring the change in temperature of some water held in a container.
In this lab, I determined the amount of heat exchanged in four different chemical reactions only using two different compounds and water. The two compounds used were Magnesium Hydroxide and Citric Acid. Both compounds were in there solid states in powder form. Magnesium Hydroxide was mixed with water and the change in heat was measured using a thermometer. The next reaction combined citric acid and magnesium hydroxide in water. The change in heat was measured as well. For the third reaction citric acid was placed in water to measure the change in heat. In the last reaction, citric acid was combined with water. The heat exchanged was again measured. It is obvious we were studying the calorimetry of each reaction. We used a calorimeter
Alcohols will be burnt to heat up water. The aim is to find out how
EG, if the water was 23 degrees I would heat the water to 33 degrees. Make sure that the fuel is weighed correctly after experiment, and recorded. By doing these checks, it means that all the experiments will be fun the same. This means the test will all be fair. Prediction I think the more bonds in the alcohol molecule structure means that more heat energy will be produced when the bonds are broken and so less fuel will be used, as the heating temperature will be higher, so it will not take as long to heat.
water has had equal amounts of time for it to heat up, again I will
be yes as I will then be able to use enthalpy change of reaction to
Investigating Factors Affecting the Heat of Combustion of Alcohols PLANNING SECTION Introduction ------------ Alcohols are organic substances, and consist of Hydrogen, Oxygen and Carbon. All alcohols are toxic but the amount that can be tolerated by the human body varies for different alcohols. For example drinking small amounts of Methanol can lead to blindness and even death.
If the length of the carbon chain within an alkanol is increased, then the heat of combustion will also increase due to a greater amount of intermolecular forces between molecules, as there are more carbon-hydrogen molecules being added to the homologous series. Thus the amount of energy required to break those bonds will be much higher, causing a greater amount of energy being released during the reaction. Therefore enhancing the mass of the hydrocarbon and change in enthalpy which will consequently increase the heat of combustion.
First of all, the reading passage claims that ethanol doesn’t solve the global warming problem, since ethanol releases carbon dioxide to the atmosphere likewise gasoline does. However, the professor contradicts this point and points out that it is true that ethanol releases CO2, where as its production from plant source counteracts the global warming. He adds that the growing of the plant absorbs carbon dioxide and removes it
Alcohol is a class of organic compounds that is characterized by the presence of one or more hydroxyl groups (-OH) attached to a carbon atom. Alcohol was unknowingly produced centuries ago when fermentation occurred to crushed grapes (Pines, 1931). In today’s society alcohol is produced for the use of household products such as varnishes, cleaning products, but is more commercially important in the liquor business. A chemical process called fermentation accomplishes the production of ethanol, the alcohol or liquor. From there, the ethanol goes through distinct processes to become the dark and clear liquors on the store shelves.