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Energy produced when burning alcohols
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The link between the number of carbon atoms in a fuel with the amount of energy it releases
Alcohols generally belong to compounds whose molecules are based on chains of carbon atoms. They usually contain one oxygen atom, which is joined to a carbon atom by a singular bond. This makes them different to other compounds. The oxygen atom is joined to the hydrogen atom as well as the carbon atom, which makes the oxygen a part of a hydroxyl group. These atoms are generally a part of a hydrocarbon chain. These alcohols can take away water from the body, in which a hydrocarbon chain has replaced a hydrogen atom. Alcohols have a general structure of CnH2n+1OH
The aim of this investigation is to see the link between the numbers of carbon atom in a fuel with the amount of energy it releases. There would be a change in the amount of energy given off that is getting greater, the more carbon atoms in the fuel, the more there are more bonds to be broken and formed, thus producing more energy. ‘In a chemical reaction, bonds in the reactant molecule are broken and new ones are formed. Atoms are rearranged. Energy has to be put in to break bonds, and energy is given out when bonds are formed.’ When the total energy put in is greater than the energy put out, the substance cools down (it is endothermic). This is expressed as Δ +ve (delta positive). If the total energy put in is less than the energy created, then the substance warms up (it is exothermic). This is expressed as Δ
-ve (delta negative).
I will investigate eight different alcohols using an alcohol or spirit burner, to measure the energy change during burning them by measuring the change in temperature of some water held by a container. This container must have a value of specific heat capacity so I could calculate heat transferred to it as well. Probably the most conductive container available for use in the classroom is a calorimeter. As well as not wasting energy in the heating of the container, I could also try to stop heat from escaping the top and edges of the container by covering it with a fitting lid. I will try to prevent the wind from blowing the flames to a different direction so all the windows must be shut. HYPOTHESIS
More energy is released as more bonds are formed, below is the list of approximate energy required to break and form all bond involved in burning alcohols
TYPE OF BOND ENERGY REQUIRED TO BREAK THE BOND (j)
Another way to control the heat is to decrease the distance between the boiling tube. and the container of the. The amount of energy released increases with the number of bonds. present in the chemical substance or fuel. That is because each bond has a certain amount of energy stored in it therefore the more bonds the more energy is stored and more energy is released if these bonds break through the combustion process.
Since 1-octanol was the least polar among 3 alcohols used in this part, so it was found to be insoluble in water but soluble in hexane. This was due to the longer chain of carbons makes compounds more hydrocarbon-like.
I think this will happen because there are more bonds in the large hydrocarbons, so it will take more energy to break them all. By having more energy acting on the hydrocarbon, means when the bonds are broken more energy will be released (an exothermic reaction). This reaction will heat the water. As the larger hydrocarbons release more energy than the smaller ones (i.e. methane) it means less hydrocarbons have to react to produce the same amount of heat energy, so less fuel is consumed.
Thus using Hess' law we can calculate the enthalpy change of reaction 3. Reaction 3: H = Reaction 1 - Reaction 2. H = -17.67 - (-88.15) =
The Enthalpy Change of Different Alcohols My aim is to compare the enthalpy change of combustion of different alcohols in relation to the structure of each molecule. The enthalpy change of combustion of a fuel is a measure of the energy transferred when one mole of the fuel burns completely. In a chemical reaction, bonds must either be made or broken, this involves an enthalpy change. The formation of bonds is exothermic, energy is lost to the surrounding; on the other hand, breaking bonds is endothermic, energy is taken in. I obtain the value for the enthalpy change of each fuel by using the formula: Energy transferred from the fuel=
Full combustion should generate two products only: carbon dioxide and water vapour. Hypothesis Within a molecule there are bond energies that hold the atoms together. When the fuel combusts, a chemical reaction takes place, this breaks the bonds, this requires energy, and makes new bonds, this gives out energy. The energy differences between the two tell us how much energy was given out or taken in. We can show this in a graph.
be yes as I will then be able to use enthalpy change of reaction to
Ethanol is the only alcohol that can be drunk safely and is found in all alcoholic drinks. Throughout this investigation I am going to investigate to different factors that affect the breakdown of an alcohol. [IMAGE]e.g. Methane (HCO) + Oxygen (O2) Carbon dioxide (CO2) + Water (H2O) Aim --- I am going to investigate increasing the chain length and see what effect there is on the heat of combustion.
Carbon dioxide or CO2 is known to be one of a number of gases that are astonishingly transparent to the visible light that falls on the Earth from the Sun, but it absorb the infra-red radiation that emitted by the warm surface of our Earth, to prevents its loss into space. Moreover, CO2 has varied considerably and this affected the Earth’s temperature. Most common source of this CO2 is known as the fossil fuel. Fossil fuels are primarily coal, hydrocarbons, natural gas, or fuel oil that formed from the remains of the dead plants and also animals. The burning fossil fuel that has been created by humans is the largest source of emissions of the carbon dioxide.
...e amounts of another gas known as methane, which also has an impact on the greenhouse effect and global warming. The last variable was alternative and nuclear energy consumption, which did not have a significant effect on carbon dioxide emissions. This is important because there is research going on for alternative energy sources and which are best for our environment. Seeing that alternative and nuclear energy did not have a significant effect on emission is very encouraging for such research and development of new technologies.
There are four different types of hydrocarbons each having a different homologous series (formula for carbon chain). These being an alkane (formula = CnH2n+2), alkene (formula = CnH2n), alkyne (formula = CnH2n-2), and an alkanol which has the same formulae as an alkane only that is has a hydroxide molecule which replaces one of the hydrogen atoms (refer to figure 3 and
...ch is used to replace natural gas. He also stated that, among the equipment used to burn the biofuel, the suspension burner have the ability to exceed 99% efficiency and whole-tree burner can reduce the cost of harvesting and handling woody fuels by about 35% (Brown, 2003). Moreover, the usage of bio-energy in long term is to provide a degree of ecological balance and climate change, avoid acid rain, reduce soil erosion and minimize water pollution (Gevorkian, 2007). Therefore, biomass is environmental friendly like solar energy. Based on the research that has been carried out regarding the synthesis of gas from biomass, the gas gasifies in the internal combustion engine. The relative energy density of synthesis gas is higher than the fossil fuel under certain conditions. In addition, the relative flame speed of synthesis gas can reduce the time for spark ignition.
The emission of carbon dioxide has contributed to 80% to the heating of the earth atmosphere. Carbon dioxide is produced due the burning of fossil fuels such as natural gas, coal and oil. The burning of fossil fuel is very important in our society today, because it is used for cooking, used to produce electricity, for heating, for cooling and also for transportation. The industrialization has led to the use of fossil fuel for running machines and driving cars. The building of fossil fuel contributes towards 80-90% of the carbon dioxide we find in our atmosphere today. When the ecosystems are altered and vegetation is either burned or took out, the carbon stored in them is relinquished to the atmosphere as carbon dioxide (What causes global climate change, 2005). Methane is another gas being produced in the process which all have served to increase the greenhouse effect in our atmosphere. Methane is produced from the cultivation of rice, from the burning of coal and from cattle, it has increased by 145% due to human
Carbon Carbon is one of the basic elements of matter (Bush 1230-1231). The name carbon comes from the Latin word "carbo" meaning charcoal. Carbon is the sixth most abundant element (Gangson). More than 1,000,000 compounds are made from carbon (Carbon (C)). "The Element Carbon is defined as a naturally abundant non-metallic element that occurs in many inorganic and in all organic compounds, exists freely as graphite and diamond and as a constituent of coal, limestone, and petroleum, and is capable of chemical self-bonding to form an enormous number of chemically, biologically, and commercially important molecules.
When gasoline burns in the engine of a car, an equal amount of work and heat appears as the energy is released. The heat from the engine warms its surroundings, the car parts, the air, and the passenger area. The heat energy is converted into the electrical energy of the radio, chemical energy of the battery, and radiant energy of the lights. The change in the sum of all of the energies formed from the burnt gasoline is equal to the “.change in energy between the reactants and products.” Biological processes, like photosynthesis, also follow energy conservation.