Preparation of Ethanol and Ethanoic Acid

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Preparation of Ethanol and Ethanoic Acid

AIM: To obtain pure samples of Ethanol (CH3CH2OH) and Ethanoic Acid

(CH3COOH) from fermented Yeast (Saccharomyces Cerevisiae).

BACKGROUND INFORMATION:

The use of yeast in food production is the oldest and most extensive

contribution made by any group of microorganisms. A most common

substrate that yeast can work with is GLUCOSE.

Glucose is a monosaccharide, which are sweet crystalline sugars that

dissolve easily in water to form sweet solutions. Monosaccharides have

the general formula (CH2O)n and consist of a single sugar molecule.

Glucose is the simplest and most common monosaccharide. It is a Hexose

sugar and therefore has the formula C6H12O6.

Glucose can exist in two possible ring forms, known as the alpha (a)

and beta (b) forms:

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The hydroxyl group on Carbon atom 1 can project below the ring (a

glucose) or above the ring (b glucose). Molecules like this, which

have the same molecular formula but a different structural formula,

are said to be ISOMERS of each other. One type of isomerism, called

sterioisomerism, occurs when the same atoms or groups, are joined

together but differ in their arrangement in space.

The existence of two isomers of glucose is important because it is

linked to the way in which polysaccharides are formed and subsequently

their roles. A glucose molecule can switch spontaneously from the open

chain form to either of the two ring forms and back again.

As glucose is respiratory substrate, it is a very important source of

energy in living organisms. Glucose is an important building block as

it is used to build up more complex carbohydrates e.g. Starch,

Glycogen and Cellulose. It is a substrate, which gets broken down by

the enzymes in the yeast.

ENZYMES are defined as biological catalysts. A catalyst is a

substance, which speeds up a chemical reaction, but remains unchanged

itself throughout the whole reaction. Enzymes are biological because

they are protein molecules made by living cells. An enzyme combines

with its substrate to form a short-lived enzyme/substrate complex.

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