Obtaining Zinc Oxide from Calamine

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Obtaining Zinc Oxide from Calamine

Introduction

Calamine is a mineral containing zinc carbonate (ZnCO₃) On heating it

decomposes as:

[IMAGE]ZnCO₃ ZnO + CO₂

(C = 12, 0 = 16, Zn = 65)

This equation allows you to calculate a theoretical conversion of

calamine into zinc oxide. As when using the theoretical conversion;

[IMAGE]ZnCO₃ ZnO + CO₂

[IMAGE]65+12+48 65+16 + 12+32

[IMAGE]125 81 + 44

This means that one mole of calamine weighs 125g and when heated it

produces 81g of zinc oxide and 44g of carbon dioxide. Therefore to

work out how much zinc oxide is produced from 1g of calamine we divide

81 by 125.

81/125 = 0.648g

To calculate how much zinc oxide is produced from 2g of calamine 0.648

is doubled:

0.648 x 2 = 1.296g

To calculate how much zinc oxide is produced from 3g of calamine 0.648

is tripled and so on when increasing the mass of calamine. On the next

page there is a table of the theoretical conversions for how much zinc

oxide is produced from using certain amounts of calamine (1g-9g)

Mass Of ZnCO₃ (g)

Mass of ZnO Produced (g)

1

0.648

2

1.296

3

1.944

4

2.592

5

3.24

6

3.888

7

4.536

8

5.184

9

5.832

Here is a graph of the results predicted from the table…………

This experiment is going to see how much zinc oxide can be obtained

from calamine. It shall also show how close to the conversion can be

achieved in practice.

Hypothesis

In a previous experiment where copper carbonate was obtained from

malachite the results showed that as the more malachite was used the

more product was produced. The relationship between the mass of

malachite used and the amount of copper oxide obtained was

proportional. Malachite and calamine are next to each other in the

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