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Indirect determination of an enthalpy change of reaction
Heat effects and calorimetry lab
Determination of the enthalpy change associated with a reaction
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The objective of the lab is to determine the heat of the reaction between magnesium and hydrochloric acid in the calorimeter. To determine the enthalpy change of the chemical reaction, a calorimeter was placed onto the workbench. A balance was place on the workbench. The calorimeter was placed onto the balance and weighed to be 18.600 grams. A thermometer was attached to the calorimeter. The initial temperature recorded is 21.5 C. 50 mL of 1M of Hydrochloric Acid was placed into the calorimeter. 0.150 grams of magnesium was added into the calorimeter. A chemical reaction had occurred and the observed temperature was 34.5 C. The calorimeter was placed onto the electronic scale and was measured to be 68.738 grams. The used calorimeter were …show more content…
In experiment’s 2rd trail, a new calorimeter was placed onto the workbench. It was placed onto the electronic scale and weighed 18.600 grams. A thermometer was attached to the calorimeter. The initial temperature was 21.5 C. 50 mL of 1M Hydrochloric Acid was placed into the calorimeter. 0.250 grams of magnesium was placed into the calorimeter. A chemical reaction occurred and the temperature recorded was 43.2 C. The calorimeter was placed onto the electronic scale and weighed to be 68.839 grams. Afterwards, the calorimeter was discarded. In the experiment's third trial, a new calorimeter was placed onto the workbench. It was then placed onto the electronic scale and it weighted 18.600 grams. A thermometer was attached to the calorimeter. The initial temperature recorded was 21.5 C. 50 mL of 1M Hydrochloric Acid was placed into the calorimeter. 0.350 grams were added into the calorimeter. A chemical reaction occurred. The recorded temperature is 51.8 C. The calorimeter was placed onto the electronic scale and the total mass is 68.921 grams. All materials were …show more content…
By dividing .350 grams of magnesium by the molar mass, 24.305 g/mol, the amount of moles used in the reaction is calculated to be .0144 moles. Afterwards, the following equation, Qrnx= -(M * C * t+ Ccal * t) , is used to determine amount of heat in the chemical reaction. M is determined by subtracting the mass of the calorimeter and its contents after the reaction, 68.921 grams., by the initial mass of the calorimeter, 18.600 grams. After the calculation, M is calculated to be 50.321 grams. t is determined by subtracting the final temperature, 51.8 C, from the initial temperature, 21.5 C. From the calculation, is determined to be 30.3 C. From the background information, Ccal is determined to be 9.30 J/°C and C is determined to be 4.18 J/g°C. By plugging the determined values into the equation, Qrnx= -(M * C *t + Ccal *t ), Qrnx, the heat of the reaction is determined to be -6655.15 J/g(c). Finally, to determine the enthalpy value of the reaction, Qrnx,--6655.15 J/g(c), is divided by the number of moles of magnesium used in the reaction, .0144 moles , the enthalpy value of the determined to be -462162.9
Two equations were used in this experiment to determine the initial temperature of the hot water. The first equation
Compared with the accepted value of –601.8 kJ/mol Mg, our experimental error was 2.46%. Introduction In this investigation the change in enthalpy will be determined from the following equation: 2Mg + O2 ® 2MgO, but in an indirect manner. Magnesium metal burns on a bright, extremely hot flame to produce magnesium oxide. It would be difficult to measure the heat of the reaction since the reaction is rapid and occurs at a high temperature (LeMay et al, 1996).
" This means that therefore the enthalpy change of a reaction can be measured by the calculation of 2 other reactions which relate directly to the reactants used in the first reaction and provided the same reaction conditions are used, the results will not be affected. We have the problem set by the experiment to determine the enthalpy change of the thermal decomposition of calcium carbonate. This is difficult because we cannot accurately measure how much thermal energy is taken from the surroundings and provided via thermal energy from a Bunsen flame into the reactants, due to its endothermic nature. Therefore, using the enthalpy changes obtained in reaction 1 and reaction 2 we can set up a Hess cycle.
Tf-Ti). Next, subtract the initial temperature, 25 degrees from the final temperature, 29 degrees putting the change in temperature at 4 °C. To calculate the heat absorbed by the water in calorimeter, use the formula (q = mCΔT). Plug in 50 mL for (m), 4.184 J for (C) and 4 °C for the initial temperature (ΔT), then multiply.
The specific heat of copper was calculated to be .425 J/goC by using the relationship of the specific heat of water and copper. The percent error of the aforementioned specific heat of copper is 9.4%. The unknown metal’s specific heat was found to be 1.104 J/goC based on data collected from the experiment, however, the true identity of the unidentified metal was revealed to be Magnesium. Given the identity of the metal, the percent error was found to be 59.33%. This percent error is incredibly high, some potential sources of this high percentage is the nature of the styrofoam cup, in that the cup could not insulate the water very well, allowing the heat energy to not be contained in the cup. Another possible source of error would be human
In this lab, I determined the amount of heat exchanged in four different chemical reactions only using two different compounds and water. The two compounds used were Magnesium Hydroxide and Citric Acid. Both compounds were in there solid states in powder form. Magnesium Hydroxide was mixed with water and the change in heat was measured using a thermometer. The next reaction combined citric acid and magnesium hydroxide in water. The change in heat was measured as well. For the third reaction citric acid was placed in water to measure the change in heat. In the last reaction, citric acid was combined with water. The heat exchanged was again measured. It is obvious we were studying the calorimetry of each reaction. We used a calorimeter
be yes as I will then be able to use enthalpy change of reaction to
When preformed each of these experiments with each temperature of water, plugging them into the equation (Delta)(Ti – hot – Tf) T Hot x Cp x Mass(Cold) = (Delta)(Tf – Ti – Cold) T Cold x Cp x Mass(Hot)(d
First, the freezing point depression of magnesium chloride was found. To begin, an ice bath was created in a 600 mL beaker filled with ice provided in the laboratory and rock salt. Next, Four different solutions with concentrations of 0.0 g (control), 0.2 g, 0.4 g, and 0.6g of magnesium chloride and 15 mL of deionized water were created. Each solution was made in a 100 mL beaker. The solutions containing magnesium chloride were stirred with a glass rod until the salt was completely dissolved. All equipment was cleaned with deionized water to minimize cross contamination. To calculate the freezing point, a Vernier temperature probe provided in the laboratory was used. The temperature probe was plugged into the GoLink!
- Temperature was measured after and exact time i.e. 1 minute, 2 minutes, 3 minutes.
The Effect of Temperature of Hydrochloric Acid on the Rate of Reaction Between Hydrochloric Acid and Magnesium
Aim: The aim of this experiment was to determine the empirical formula of magnesium oxide.
The Effect of Concentration of Hydrochloric Acid on the Rate of Reaction with Magnesium Aim: To investigate the effect of concentration of hydrochloric acid on the rate of reaction with magnesium Prediction: As the concentration of the hydrochloric acid increases, so will the rate of reaction Hypothesis: In a reaction, particles of two different reactants react together to form a product. The reaction only takes place on account of two things, if the particles collide, and if the collision has enough 'activation energy'. The two reactant particles, in this case magnesium particles and hydrochloric acid particles, must collide with each other on the correct 'collision course'. If this does not occur then no chemical reaction will take place. The reaction must also have enough energy, this can be affected by temperature, the more heat the particles have the faster they move and so the more energy therefore more chance of successful collisions.
Investigating the Effects of Temperature on the Rate of Reaction between Magnesium and Hydrochloric Acid
For this experiment, consider your system to consist of mixing a given mass m1 of a ?hot" specimen with specific heat c1 at te...