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Experiment with magnesium ribbon and hydrochloric acid
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Determination of the Valency of Magnesium
Objectives:
In this experiment, we can know about the quantitative relations
between amounts of reactants and products of a reaction so that the
stoichiometry reaction can be determined by a known mass of magnesium
and a measured collection of hydrogen gas.
Introduction:
In chemistry, stoichiometry is the study of the combination of
elements in chemical reactions. Stoichiometry refers to the relative
number of atoms of various elements found in a chemical substance and
is often useful in characterizing a chemical reaction. The related
term stoichiometric is often used in thermodynamics to refer to the
"perfect mixture" of a fuel and air.Stoichiometry is often used to
balance chemical equations. In this experimet, a known starting mass
of magnesium and the measured collection of hydrogen gas will be used
to determine the reaction stoichiometry.
This experiment determines the stoichiometry of a reaction of
magnesium and HCl. The relationship between moles of magnesium reacted
and moles of hydrogen produced are plotted. Magnesium Ribbon is a
strip of Magnesium that is solid at room temperature. When mixed with
hydrochloric acid it produces Magnesium Chloride, which is a liquid
and Hydrogen gas.
The below is the equation that occurs:
Mg + XHCl à MgClx + [IMAGE]H2
The known amount of the magnesium is reacted with large excess of HCl
, and the volume of H2 is measured. As HCl is in excess, all the
magnesium will be consumed, and the yield of both MgClX and H2 depend
only on the amount of magnesium. A comparison of the amount of
hydrogen produced with the amount of magnesium consumed will enable X
value to be determined.
Apparatus and Materials :
· Magnesium ribbon
· HCl(0.5M)
· Burette (50cm3)
· Pipette (25cm3)
· Retort stand
· Electrical Balance
· Watch glass
· Beaker(500cm3)
· Gauze
· Funnel
· Rubber band
· Glass rod
· Thermometer
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If there is not enough energy no reaction takes place. In a solution of 0.5M hydrochloric acid, there are less hydrochloric acid particles compared to that of 2M hydrochloric acid, therefore, there are less particles to react with magnesium particles thus meaning less chance of collisions between the two reactants: [IMAGE] Therefore, as the concentration of the hydrochloric acid is increased, the chances of collisions increase thus giving a faster rate of reaction. Apparatus: Beaker Hydrochloric acid Distilled water Measuring cylinder Pipette Test tubes Test tube rack Diagram: [IMAGE] Method: Measure out 10cm3 of hydrochloric acid, as the concentration requires, for each concentration its composition is: Moles Volume HCl Volume Water 2M 10 cm³ 0 cm³ 1.5M 7.5 cm³ 2.5 cm³ 1M 5 cm³ 5 cm³ 0.5M 2.5 cm³ 7.5 cm³ 0M 0 cm³
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Firstly, we need to keep the chemical at a constant concentration. So, in this experiment we have chosen to keep hydrochloric acid at a constant concentration (5cm3). We could have, however, used Sodium Thiosulphate as a constant, but we had chosen to use Hydrochloric acid. Next, we must make sure that the solution is kept at a constant volume throughout the experiment. If the volume is different, then it could give different results if it was at a constant volume.