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An Investigation into Electrolysis - Copper Sulphate
Introduction
Decomposition caused by electricity is called electrolysis. The
electrical energy causes a chemical change. When a salt is dissolved
in water, its ions become free to move so the solution can be
"electrolyzed." The products of the electrolysis depend on the
chemical solution, its strength and the type of electrode. The cathode
is negatively charged and therefore attracts to it positive ions. E.g.
hydrogen. The more reactive substance stays in the solution whereas
the less reactive is released and appears as a gas (hydrogen) or a
coating of metal. At the anode (positively charged) the negative
charges are given up; for example chlorine or oxygen ions become
elements.
Electrolysis is used to produce gases or purify metals.
PLAN
Aim: To find out if the current being transferred through copper
sulphate affects the amount of copper transferred.
Prediction: I predict that as the amount of electrical current is
passed through the copper sulphate solution more copper will be
transferred. I also predict that the rise in electrical current and
the rise in copper transferred will be related, and follow a trend.
e.g.
Text Box: Copper Transferred[IMAGE]
I believe that as the current doubles so will the amount of copper
transferred.
E.g. 1amp = 0.1 gram of copper transferred - 2amps = 0.2 grams of
copper transferred.
I think this will happen because it is logical that when something is
doubled the affected will be doubled as well. Also to back up my
theory is Faraday's Law:
Faraday's First Law of electrolysis states that:
"The mass of any element deposited during electrolysis is directly
proportional to the number of coulombs of electricity passed"
Faraday's Second Law of electrolysis states that:
"The mass of an element deposited by one Faraday of electricity is
equal to the atomic mass in grams of the element divided by the number
of electrons required to discharge one ion of the element."
Research:
I have researched other possible ways to work out a rough idea of what
An atom, by definition, is the smallest part of any substance. The atom has three main components that make it up: protons, neutrons, and electrons. The protons and neutrons are within the nucleus in the center of the atom. The electrons revolve around the nucleus in many orbitals. These orbitals consist of many different shapes, including circular, spiral, and many others. Protons are positively charged and electrons are negatively charged. Protons and electrons both have charge of equal magnitude (i.e. 1.602x10-19 coulombs). Neutrons have a neutral charge, and they, along with protons, are the majority of mass in an atom. Electron mass, though, is negligible. When an atom has a neutral charge, it is stable.
The purpose of this lab was to to cycle solid copper through a series of chemical forms and return it to its original form. A specific quantity of copper undergo many types of reactions and went through its whole cycle, then returned to its solid copper to be weighted. We observed 5 chemical reactions involving copper which are: Redox reaction (which includes all chemical reactions in which atoms have their oxidation state changed), double displacement reaction, precipitation reaction, decomposition reaction, and single displacement reaction.
== == I completed a table to show my results, here is the table: Table 1. Results of different changes of substances Part A Copper (II) Sulfate and Water Reactant description Water (reactant): Color: Colorless Transparency:
this is the area that one mole of any gas will occupy. Then I will
Metals contain a sea of electrons (which are negatively charged) and which flow throughout the metal. This is what allows electric current to flow so well in all metals. An electrode is a component of an electric circuit that connects the wiring of the circuit to a gas or electrolyte. A compound that conducts in a solution is called an electrolyte. The electrically positive electrode is called the anode and the negative electrode the cathode.
When a solution conducts electricity, the charge is carried by ions moving through a solution. Ions are atoms or small groups of atoms that have an electrical charge. Some ions have a negative charge and some have a positive charge. Pure water contains very few ions, so it does not conduct electricity very well. Not all substances are made up of ions. Some are made of uncharged particles called molecules. Sugar is such a substance. When sugar is dissolved in water, the solution does not conduct electricity, because there are no ions in the solution. That's why in Hands-on Squishy Circuits, the sugar PLAY-DOH did not produce electricity. The salt had ions in it to produce the electricity needed to make the LEDs light up.
To investigate the temperature change in a displacement reaction between Copper Sulphate Solution and Zinc Powder
are left in the solution, the more time there is for the copper to be
Investigation of Positively and Negatively Charged Electrons To try and find out if positively charged electrons deposit to the negatively charged electrons. This means, the electrons in the cathode attract electrons from the anode so they move towards the cathode from the anode. Prediction: I think that as the electrons move from the anode to the cathode, the mass of the anode to the cathode, the mass of the anode decreases whilst the mass of the cathode increases. I can support the point I've made above by faradays law which is: Faraday's Second Law of electrolysis states that: "The mass of an element deposited by one Faraday of electricity is equal to the atomic mass in grams of the element divided by the number of electrons required to discharge one ion of the element. " Hypothesis: The mass of the anode should decrease whilst the mass of the cathode should increase because positively charged electrons get attracted to the negatively charged electrons.
of Copper Sulphate. To do this I plan to work out the amount of water
1.) Gas Syringe 100cm³ - I chose this as it is easy to measure the
The cell anode is usually a piece of the metal to be plated from solution; this enables the anode reaction of metal dissolution to replace the metal ion lost from solution by the cathodic decomposition. Factors There are many various factors that affect the mass deposited during electroplating:- 1). Current (A) - An increase in the amount of current increases the amount of substance deposited in a fixed amount of time, because there is more energy available to move ions/electrons to the cathode from the anode. A smaller current will pump fewer copper ions from the anode to the cathode in the same amount of mass gained on the cathode is lower. 2).
Diffusion and solubility is the most important mechanism in reaction kinetics of the battery. First, porous cathode must have good oxygen path for oxygen to pass through to electrolyte. At the same time, diffusion of the lithium ions from anodic side is important.
At the cathode the hydrogen ions gain an electron. They are discharged and are converted into hydrogen gas: 2H (+) + 2e (-) → H2 At the anode, the hydroxide, not the sulphate ions are discharged. Water and oxygen gas are formed: 4OH (-) → 2 H2O + O2 + 4e (-) The hydrogen gas can be collected and measured. The greater the volume of hydrogen gas formed over a set period of time, the faster electrolysis is occurring.
Mechanism : The metal which is higher in electrochemical series forms the anode and the metal which is lower in electrochemical series forms the cathode. The difference in electrochemical potentials of the 2 metals generates a potential difference between them. The potential difference between two dissimilar metals is the driving force for the destructive attack on the active metal (anode). Current flows through the electrolyte to the more noble metal (cathode) and the less noble (anode) metal will corrode. The conductivity of electrolyte will also affect the degree of