ZOE Sealers

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I.ZnO/Eugenol based sealers:
This group of sealers encompasses a large number of products, they have relatively the same composition, but with some additives to improve the properties of the sealer.
The composition of ZOE sealers:
Sealer Powder Liquid
Rickert's sealer Zinc oxide (41.2 parts)
Precipitated silver (30 parts)
White resin (16 parts)
Thymol iodide (12.8 parts) Oil of clove (78 parts)
Canada balsam (22 parts)
Grossman's Sealer Zinc oxide reagent (42 parts)
Staybelite resin (27 parts)
Bismuth subcarbonate (15 parts)
Barium sulfate (15 parts)
Sodium borate, anhydrous (1 part) Eugenol
Wach's Sealer Zinc oxide (10 g)
Calcium phosphate (2 g)
Bismuth subnitrate (3.5 g)
Bismuth subiodide (0.3 g)
Heavy magnesium oxide (0.5 g) Canada balsam (20 ml)
Oil of clove (6 ml)
Tubliseal Base and Accelerator Tubes
Zinc oxide (57.4%)
Bismuth trioxide (7.5%)
Oleoresins (21.25%)
Thymol iodide (3.75%)
Oils (7.5%)
Modifier (2.6%)
Setting Reaction:
ZOE sealers set in a humid environment, forming ZOE chelates, taking about 24 hours. Additives, such as colophony, dicalcium phosphate, or zinc acetate can hasten the setting reaction. The setting reaction is reversible – hydrolytic conditions may cause the release of eugenol and zinc ions.

Advantages and Disadvantages of ZOE sealers:
Sealer Advantages Disadvantages
Rickert's Sealer It is germicidal SILVER CONTENT which may results in discoloration of tooth structure if not removed meticulously from the crown and pulp chamber with xylol
Excellent lubricating and adhesive qualities
Sets in about half an hour.
Sealer Advantages Disadvantages
Grossman's Sealer Minimal degree of irritation Zinc eugenate may decompose in the presence of water through the release of eugenol, making it weak ...

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...fect against enterococcus fecalis but still higher than AH26.
• High solublility (3.415) if compared with AH plus(0.21%).

4. EndoREZ:
It is dual cured self-priming methacrylate-based root canal sealer/filler which is hydrophilic in nature.
Composition:
- 2,2 (p-tolylimina) diethanol - Zinc oxide
- Triethylene glycol dimethacrylate (TEGDMA) - Barium sulfate
- Diurethane dimethacrylate (DUDMA) - Pigments
- Benzoyl peroxide
Properties:
• Hydrophilic characteristics which provides high penetration into dentinal tubules and thus allow proper sealing.
• Its radiopacity equivalent to gutta percha that simplifies radiographic interpretation.
• Superior resistance to microbial leakage (compared to AH plus).
Disadvantages:
• Causes tissue inflammation.
• High solubility.

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