3 Bromine chain ends of the polymer were altered into an azide end group and then reacted with terminal alkynes to make diverse functional end groups. 3 All from resource 5____ High effiencey reaction , solved many problems in polymer science – concerning : a) poor degree of functionalization with many usual methods of polymerization concerning star- , graft-
The goal of this lab is to exemplify a standard method for making alkyne groups in two main steps: adding bromine to alkene groups, and followed by heating the product with a strong base to eliminate H and Br from C. Then, in order to purify the product obtained, recrystallization method is used with ethanol and water. Lastly, the melting point and IR spectrum are used to determine the purity of diphenylacetylene. This experiment was divided into two main steps. The first step was the addition of
Due to this being a terminal alkyne, only one product will be formed. Techniques such as simple distillation, reflux, and gravity filtration were used to produce and separate the product from the mixture that it was in. When performing this lab using only one equivalent of alkyne produced a low percent of 1%. The low yield is a result of using one equivalent instead of two. The purpose of this experiment is to preform a hydration reaction and tautomerism of the alkyne formed, which in this case is
Purpose: To help students identify the functional groups in a mixture of two compounds by interpreting the IR spectroscopy, measuring the boiling point, comparing the physical and chemical properties of an unknown with a known substance. In addition, students will learn how impurities affect the boiling point and solubility of a substance. Procedure: The student will read the IR spectroscopy of the unknown first. Then perform various tests and measure the boiling point. Beilstein Test The Beilstein
trapped in sediments were converted by heat and pressure into crude oil. The most abundant of these mixtures are the ones containing hydrogen and carbon only. These hydrocarbons can take on a number of different forms, i.e. alkanes, alkenes and alkynes. They vary in size and shape and viscosity. By manipulating these chains of hydrocarbons you can create any number of useful substances as they are very adaptable. However there are lots of compounds that also contain some of the following; oxygen
hydrolysis. Dehydration is an elimination reaction of an alcohol involves the loss of an OH from one carbon and an H from an adjacent carbon. Overall, this amounts to the elimination of a molecule of water, resulting in a pi-bond formation of an alkene or alkyne. In most of the dehydration of alcohol, heat and catalyze are needed in the reaction. Sulphuric acid (H2SO4) and phosphoric acid (H3PO4) are the most commonly used acid catalysts. The dehydration process can be carried out by in two ways. The first
combustion whilst also effecting the reliability of the calculations. There are four different types of hydrocarbons each having a different homologous series (formula for carbon chain). These being an alkane (formula = CnH2n+2), alkene (formula = CnH2n), alkyne (formula = CnH2n-2), and an alkanol which has the same formulae as an alkane only that is has a hydroxide molecule which replaces one of the hydrogen atoms (refer to figure 3 and
The resulted products after any thermo-chemical process are: • A solid elements (residue), known as char • A gas product( syn gas) • A tarry liquid of compound composition, familiar as “tar”, often present in liquid vapour phase at process temperature As per the reported by Hallgren et.al. (1996), the uniqueness of the products like as gas, liquids and solid, based on a broad range of factors just like as the chemical as well as physical distinctiveness of the feedstock, the heating rate (C.V),
Carbon Compounds 23.1 What is carbon Compounds? carbon compounds are far more numerous and varied than compounds formed from other elements there are millions of different carbon compounds most are combinations with hydrogen, oxygen, nitrogen, sulfur, phosphorous, and the hologens some general and physical properties of carbon atoms are : non electrolytes, or very weak electrolytes low melting points compounds made solely from carbon and hydrogen are generally non-polar
Chapter-2 Efficient ZnO NPs catalyzed Friedlander annulations in the synthesis of diverse quinolin-2(1H)-ones 2.1.1 INTRODUCTION OF QUINOLINONES AND QUINOLINES The quinolinone and quinoline ring is highly prevalent in natural compounds. There are synthetic and potential agents, which show various pharmacological properties (Priya et al., 2012). Quinolinones are important structural intermediates for synthesis of functionalized quinolines (Baston et al., 2000). Quinolines have demonstrated various