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Law of thermodynamics
Importants Of Laws Of Thermodynamics
Law of thermodynamics
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Thermodynamics is the study of work, heat, and the energy of a system (NASA, 2010). To help explain in more detail the properties of thermodynamics are the laws of thermodynamics. The first law explains that a system’s internal energy can be increased by adding energy to the system or by doing work on the system (Serway & Vuille, 2012). An internal energy system is the sum of both its kinetic and potential energies. The first law more simply states that the change in internal energy of a system is caused by an exchange of energy across the system, typically in the form of heat, or by doing work on the system. This relationship can be represented by the equation:
ΔU = Q + W
ΔU is the change in internal energy, Q is the energy exchanged (heat), and W is the work done on the system.
Often, energy is exchanged with a gas while work is either done on the gas or by the gas. When work is done on the gas, work is negative; whereas, when work is done by the gas, work is positive (Serway & Vuille, 2012). The internal energy of an ideal gas is represented by the expression:
U = (3/2)nRT
For a monatomic gas where its particles consist of only single atoms, its change in internal energy is represented by the equation:
ΔU = (3/2)nRΔT
n is the number of moles, R is the gas constant (8.31 J/Kmol), and ΔT is the change in temperature measured in Kelvins.
Temperature is measured using many different units throughout the world. Americans in the U.S. typically measure temperature in degrees Fahrenheit. More commonly used throughout the world is degrees in Celsius. In physics, Celsius is also commonly used, along w...
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...ics is also incorporated into the technology of our world, including how energy is taken from a refrigerator and delivered as heat to the kitchen; how a heat engine takes in energy by form of heat and uses that energy to create new mechanical and electrical energy; or how an air conditioner uses a heat pump to extract energy from the cold outside air and delivers energy in the form of heat to the warmer inside air. By understanding how thermodynamics is a study of physics, it will make it easier to recognize its influence on our everyday lives as well.
References
1. Department of Physics. (2010). Physics 174/184 lab manual. Oxford: Kendall Hunt.
2. NASA. (2010). What is thermodynamics?. Retrieved from http://www.grc.nasa.gov/WWW/k-12/airplane/thermo.html
3. Serway, R. A., & Vuille, C. (2012). College physics. (9th ed.). Boston: Cengage Learning.
Thermodynamics is essentially how heat energy transfers from one substance to another. In “Joe Science vs. the Water Heater,” the temperature of water in a water heater must be found without measuring the water directly from the water heater. This problem was translated to the lab by providing heated water, fish bowl thermometers, styrofoam cups, and all other instruments found in the lab. The thermometer only reaches 45 degrees celsius; therefore, thermodynamic equations need to be applied in order to find the original temperature of the hot water. We also had access to deionized water that was approximately room temperature.
The thermometer’s original temperature before coming in contact with an outside object is represented by T. ∆T/∆t is the average temperature of the digital thermometer. represents the temperature of the heat flowing object. In this lab, the temperature of the air is represented by Tair=T. To= Thand is the temperature of the hand.
to an unfavorable free energy change for the process. Once added to a system, before equilibrium
type of energy is lost or gained, and whether or not a factor that is
The first law of thermodynamics simply states that heat is a form of energy and heat energy cannot be created nor destroyed. In this lab we were measuring the change in temperature and how it affected the enthalpy of the reaction.
+70.48 kJ.mol. Comparing the value +70.48 kJ.mol-1 to the theoretical value of this enthalpy change (101kPa, 298K): +177.8 kJ.mol-1, there is a huge difference. Percentage error is calculated by: 100 x Theoretical Value - Actual Value. Theoretical Value Percentage error = (177.8 - 70.48) / 177.8 = 60.4%. Considering the scatter diagrams, they show the expected positive correlation.
energy was given out or taken in. We can show this on a graph. Alcohol
So in equation form this is: pV = constant if T is constant Amontons discovered that for a fixed mass of gas at constant volume, the pressure is proportional to the Kelvin temperature. So in equation form this is: p µ T if V is constant Shown below this is represented on graphs in (oC) and (K). [IMAGE] P [IMAGE] [IMAGE] q/oC -273 0 [IMAGE] P 0 T/K Charles discovered that for a fixed mass of gas at constant pressure, the volume is proportional to the Kelvin temperature. So in equation form this is: V µ T if p is constant.
Throughout Thomson’s life he made many contributions to science. These include discoveries in thermodynamics and the age of the Earth, as well as innovating the Transatlantic Cable and inventing a tide meter. After exploring thermodynamics for some time, he developed the second law of thermodynamics. This law states that there cannot be a reaction that is completely efficient; a portion of the energy is lost to heat in each reaction. It also says that heat flows to areas that...
Heat is thermal energy being transferred from one place to another, because of temperature changes. This can take place by three processes. These three processes are known as conduction, convection, and radiation.
Energy is a kind of quantitative properties that exist in the earth describing ecosystem or object state. Energy can be transformed among a number of forms that may each manifest and be measurable in differing ways (Wikipedia2013). Energy existed in the ecosystem with different form. Meanwhile, it does not cycle through ecosystems but instead enters ecosystems and is used up within ecosystems (InstaEDU 2013). Also, energy flow is the process by which energy moves throughout an ecosystem and energy existed in difference energy flows in ecosystem such as biological, chemical and physical. The purpose of this essay is to describe and explain different energy flows in our daily life and how these energy flows vital to human.
In order for a system to gain energy the surroundings have to supply it, and visa versa when the system looses energy the surroundings must gain it. As the energy is transferred it can be converted form its original form to another as the transfer takes place, but the energy will never be created or destroyed. The first law of thermodynamics, also known as the law of conservation of energy, basically restates that energy can’t be destroyed or created “as follows: the total energy of the universe is a constant.” All around the conservation of energy is applied. When gasoline burns in the engine of a car, an equal amount of work and heat appear as the energy is released. The heat from the engine warms its surroundings, the cars parts, the air, and the passenger area. The heat energy is converted into the electrical energy of the radio, chemical energy of the battery, and radiant energy of the lights. The change in the sum of all of the energies formed from the burnt gasoline would be equal to the “…change in energy between the reactants and products.” Biological processes, like photosynthesis, also follow energy conservation. The green plants convert the radiant energy emitted by the Sun into useful chemical energy, such as the oxygen that we breathe. The energy transferred between any surroundings and any system can be in the form of various types of work, chemical, mechanical, radiant, electrical, or heat.
During the seventeenth century, the modern science of physics started to emerge and become a widespread tool used around the world. Many prominent people contributed to the build up of this fascinating field and managed to generally define it as the science of matter and energy and their interactions. However, as we know, physics is much more than that. It explains the world around us in every form imaginable. The study of physics is a fundamental science that helps the advancing knowledge of the natural world, technology and aids in the other sciences and in our economy. Without the field of physics, the world today would be a complete mystery, everything would be different because of the significance physics has on our life as individuals and as a society.