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Research papers on titanium
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TITANIUM
DISCOVERY : Titanium was first discovered in black sand known as “ILMENITE” , a mixture of titanium oxides and iron oxides by “ WILLIAM GREGOR”, the pastor of mannacan of parish in the year 1791 at England, and named his new metal as “MANACCANITE”, after his discovery a German chemist “MARTIN KLAPROTH” named it as “TITANIUM” after the TITANS, greek’s mythological beings of the earth and the name was preferred by other chemists but they believed Gregor as the original discoverer.Till 1910 pure titanium is not isolated and it was done by “ Mathew Hunter” after 119 years of its discovery.
Titanium was placed in 4B Group in d-block elements in periodic table and it has many applications.
Isotopes: Till now 26 isotopes are
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known ranging from Ti-38 to Ti-63 and among them there are five stable alloys with atomic masses from 46-50 among them Ti-48 is most abundant in earth with 73.8 percent of all natural titanium. Titanium stands in 9th place in most abundant elements I earth’s crust. Ti is present in human body, coal ash, plants, sun, meteorites etc... Rocks from Apollo 17 mission to the moon contains 12.02 percent of titanium dioxide. Atomic number: 22 Atomic weight: 47.28 a.m.u Electronic configuration: [Ar] 4s^2 3d^2 Symbol: Ti Melting point: 1933 K Boiling point: 3560 K Appearance: dark-grey shiny metal Oxidation states: 4, 3 Atomic radius: 147 ppm Atomic volume: 10.66 cc/mol Specific heat: 0,523 J/gm- mol at 293 K Covalent radius: 132 pm Fushion heat: 18.8 kg/mol Density: 4.54 gm/cc PROPERTIES OF TITANIUM: Titanium is equally strong as steel but the main thing it is less dense, very light and very strong.
As we mention earlier titanium is 9th most abundant metal in earth’s crust and it is more available in the regions of south Africa and it is available as TiO2(titanium di oxide).
But the main problem is extraction of titanium from titanium di oxide. Because titanium atoms bound strongly to oxygen and it is difficult to get the metal. Although it is very difficult to extract people want it because of its own properties which are as follows
Titanium is having low specific gravity
Titanium is having high specific strength
Titanium is having high corrosive resistance and it is “nonmagnetic in nature” .since it is nonmagnetic in nature if we want to do experiments in high magnetic field we can’t use steel because steel apparatus will be pulled away by the magnetic field so we can use titanium apparatus in experiments dealing with high magnetic field.
The important thing in titanium is not only light but also very strong so it can be used for making vehicles which will consume less fuel and we can expect the vehicle of low cost and it is “fuel efficiency” matters
here. Titanium does not reacts with water with this we can make miracles with this metal and it is non-toxic in nature and it is a “bio compatible material” Because it is non-toxic it can be used in “artificial hip implantation” in human body as it is light so we can easily move your leg. Titanium acts as a “catalyst” while making polythene, material which is used to made plastic buckets and another plastic materials. Titanium is better catalyst than aluminium because with 1 gm of titanium as a catalyst we can get some tons of plastic. Here in adjacent photos we can observe the “Titanium’s artificial hip implantation” Here this is “Lockheed SR-71 Blackbird made up of titanium
Travertine TRAVERTINE is a form of massive calcium carbonate, CaCO3 resulting from deposition by springs or rivers. It is often beautifully colored and banded as a result of the presence of iron compounds or other (e.g., organic) impurities. This material is variously known as calc-sinter and calcareous tufa and (when used for decorative purposes) as onyx marble, Mexican onyx, and Egyptian or Oriental alabaster. Travertine is generally less coarse-grained and takes a higher polish than stalactite and stalagmite, which are similar in chemical composition and origin. Travertine, the stone of the Colosseum and St. Peters as well as of several structures in New York and Philadelphia, is not a volcanic tufa but calcareous sediment that was deposited on the ground by the hot springs that first began to flow during the earliest eruptions of the Alban volcanoes. The best quality, in fact the only reliable one in Latium, is that which is found between Bagni and the Sabine hills below Tivoli. Lanciani, who has fascinatingly described the quarries there, estimated that five and a half million cubic meters of stone had been extracted from the ancient quarry alone. And yet, because of its position under a flat grass-grown plain, the Romans did not discover the existence of this remarkable stone till after the middle of the second century B. C.; and even after that they failed for a century to develop a system of extracting the stone in a sufficiently easy way to make the extensive use of it practicable. In the later decades of the second century B. C. it displaced peperino for inscriptional monuments for obvious reasons. Its employment in large structures cannot with certainty be posited before the construction of the Mulvian bridge in 109,...
Strontium was discovered by Adair Crawford, an Irish chemist, in 1790 while studying the mineral witherite (BaCO3). When he mixed witherite with hydrochloric acid (HCl), he did not get the results he expected. He assumed that his sample of witherite was contaminated with an unknown mineral, a mineral he named strontianite (SrCO3). Strontium was first isolated by Sir Humphry Davy, an English chemist, in 1808 through the electrolysis of a mixture of strontium chloride (SrCl2) and mercuric oxide (HgO). Strontium reacts vigorously with water and quickly tarnishes in air, so it must be stored out of contact with air and water. Due to its extreme reactivity to air, this element always naturally occurs combined with other elements and compounds. Strontium is very
The Beryllium element, an alkaline earth metal which belongs to group II of the periodic table, was first discovered in 1798 by L.M. Vauquelin. Vauquelin,a French chemist, was doing work with aluminum and noticed a white powder that was nothing like that of aluminum or any of its derivatives. Vauquelin named this mystery powder, gluinium because of its sweet taste was like that of glucose. In 1828, Wohler, a German metallurgist reduced it to its metallic form and renamed it beryllium.(figure 2)
...stainless steel and Co-Cr alloys which results in poor rigidity. Alongside this, titanium is a light material which would make it difficult to see under x-ray imaging (Hanawa, 2009).
These kinds of polymers have both some advantages and disadvantages. Although they are bioactive and biodegradable and provide high comppressive strength, Degradation of such polymers leads to undesired tissue response due to producing acid formation in degradation process. Metallic scaffolds are another method for bone repair and regenaration. They provide high compressive strength and enormous permanent strength. Metallic scaffolds are mainly made of titanium and talium metals. The main disadvantages of metallic scaffolds are not biodegradable and also discharge metal ions. Recent studies in metallic scaffolds mainly focus on biodegradable materials which can be used improve bioactivity of metals such as titanium.
Pounding metal and fabricating metal in thin sheets and sections that humans need or want has a long history. The discovery of how to make and control fire made extracting metals form or more efficient instead of having to find almost pure nuggets of metal. In many civilizations copper was the metal they used but that was succeeded by bronze eventually it is made of copper and tin.
Mr. Cronstedt discovered nickel in a mineral called niccolite. He originally planned to extract copper from this new mineral but got none at all. This is why nickel, at first, was called "false copper". Instead, Cronstedt got a silvery-white metal, which was eventually used for other things.
However, the largest use of this metal is in the form of titanium (IV) oxide, which accounts for over 96% of titanium consumption worldwide. Because of its excellent physical properties, which are the lack of colour, high refractive index and chemical inertness, titanium dioxide is the principal inorganic synthetic pigment on the market with over 3,000,000 tonnes per annum produced accounting for 66% of the global production capacity of pigments as shown in table 1: [3]
...mpositional control needed and also the reactivity of the titanium. Fatigue failure has been known to occur with nitinol because of the extreme amounts of fatigue strain that it is necessarily exposed to. This is because it is still not completely defined how durable nitinol is, so it cannot be known what to use it for as it is the best of all metals known in this case. So it is used for the highest demanding applications but in some cases it can’t handle the pressure sustained. Another use for nitinol is a temperature control system, which would work by changing shape can activate a variable resistor or switch which would control the temperature, this is a situation where it is very significant for nitinol to be a smart material otherwise this system would simply just not work. There are many others but they are not really relevant to the engineering industry.
BIBLIOGRAPHY Advantages to Aluminum. http://www.kaiserextrusion.com/advantage.html. November 28, 2000. Aluminum Facts. http://www.epa.gov/seahome/housewaste/src/alum.htm. November,28 2000. Bowman, Kenneth A. World Book Encyclopedia. "Aluminum." Chicago: World Book, Inc., 1992. Cobb, Cathy. Creations of Fire. New York: Plenum Press, 1995 Geary, Don. The Welder's Bible. Pensilvania: Tab Books, 1993. Knapp PhD, Brian. Aluminum. Connecticut: Grolier, 1996. Newmark, Dr. Ann. Chemistry. London: Dorling Kindersley, 1993. Walker, John R. Modern Metalworking. Illinois: The Goodheart-Willcox Company, Inc., 1985.
The alloy is then quenched in water to trap or hold the alloy at this desired structure.
Platinum was very difficult to work with, and prone to being weakened by heating and oxygen
However, most metals in their natural states are less than the desired choice for the jobs they are required to do. For example, iron, although it is an incredibly strong metal in its natural form, it is delicate and rusts quite quickly in damp air. So to enhance the properties of the metal they are combined with other substances to create an alloy, which are often used instead of pure metals to generate a more durable product.
Aluminum is an element in the boron group with a symbol of Al, and an atomic number of 13. Aluminum is a very soft metal when pure but becomes strong and hard when alloyed, a malleable metal with a silvery gray color. Aluminum is a very reactive element so it is found in nature combined with other elements. Aluminum resists corrosion by the formation of a self-protecting oxide coating. Aluminum is the third most abundant element in the Earth’s crust, following oxygen and silicon. It makes up approximately 8% by weight of the Earth’s surface. Although this is evident, it is also apparent that aluminum is never found by itself in nature. All of the earth’s aluminum has combined with other elements to form compounds and in order to create new aluminum products; it has to be taken out of that specific compound. Aluminum does not rust like other elements, therefore it always remains strong and shiny, which means reused aluminum is almost identical to a brand new piece of metal. An electrochemical process creates aluminum. An electrochemical process is “the direct process end use in which electricity is used to cause a chemical transformation” ( E.I.A. Government). Major uses of electrochemical processes occur in the aluminum industry in which alumina is reduced to molten aluminum metal and oxygen, where than the aluminum can be used into making several different materials. Electrochemical processes, although very useful, can have serious environmental consequences. To help reduce the consequences that the production of aluminum creates, the idea of aluminum recycling comes into play.
Diamagnetic materials are very weak and not permanent and it persists only while an external magnetic field is applied. It is induved by a change in the orbital motion of the electrons due to an applied magnetic field. Paramagnetic materials are also categorized as antiferromagnetic and ferrimagnetic. The magnetic moment coupling between adjacent atoms/ions results in antiparallel alignment and the alignment of spin moments is exaclty in opposite directions are termed as antiferromagnetism. Manganese oxide (MnO) displays this behaviour (2). Different types of magnetic materials available are Ferrites (Ceramics), Alnico, Samarium cobalt, Neodymium (Neo) and bonded magnets.