Thermal Analysis Essay

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Thermal properties of material (Tg, Tm, Td) are those properties that response to temperature. They can be studied by thermal analysis techniques including DSC, TGA, DTA and dielectric thermal analysis. The nanometer-sized of inorganic particles incorporated into the polymer matrix can improve thermal stability by acting as a superior thermal insulator and as a mass transport barrier to the volatile products generated during decomposition [117]. Khanna et al. [57] reported the thermal (TGA) analysis of the PVA/Ag nanocomposite. They observed that the decomposition profile starting at about 330 ◦C and continuing till about 430 ◦C. They also found the PVA/Ag nanocomposites have higher thermal stability than the PVA alone. Mbhele et al. [99] also observed that that the pure PVA starts decomposing at about 280 ◦C and …show more content…

They also reported that the thermal stability of PVA/A g nanocomposite was superior to that of pure PVA. Thermal (TGA) properties of the composite films have been studied by Uddin et al. [62] who observed that the first degradation temperature (below 300 ◦C) with no difference with the pure PVA. Whereas, the second degradation temperature (at the higher temperature region above 300 ◦C) of the film is ∼40 ◦C higher than that of pure PVA indicating enhanced thermal stability of nanocomposite films. Also, the DSC thermograph of the nanocomposite films was performed. It was found the pure PVA film exhibits melting peak at 227 ◦C . But the DSC melting peaks in the nanocomposite appear at 220 ◦C lowered by 7 ◦C with respect to pure PVA film. Ananth et al. [58] studied the DSC analysis for the in-situ and ex-situ synthesis of the PVA/ Ag nanocomposites films. They found that (in the case of ex-situ PVA/Ag) the increase in the Tg after the incorporation of Ag nanoparticles into the PVA. The authors explained this behavior on the basis of interactions of the embedded Ag nanoparticles with the PVA chains resulting in the reduction in the

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