Spectroscopy Essay

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Objective:
This paper is the summary of the infrared spectroscopic technique.
Introduction:
Spectroscopy basically involves the study of the interaction of radiated energy with matter. These different radiations could be used to study chemical and physical material properties of different atoms. Colors of light differ in wavelength and energies and when they interact with matter, the light is either scattered, reflected, transmitted, absorbed, reflected or fluorescence. The interaction makes vibrational, electronic or nuclear changes in energy levels. This difference between energy levels includes a range of electromagnetic spectrum. Types of electromagnetic radiation include gamma rays, x-rays, ultraviolet, visible, infrared, microwaves and radio wave. Energies, wavelengths, frequencies, or wave number can be used to describe the radiations.

Infrared spectroscopy (IR spectroscopy) is a type of spectroscopy that involves the infrared region of the electromagnetic spectrum. It is one of the most important analytical methods widely used. It is a method that is used to measure how much infrared radiation is absorbed by sample materials. Different functional groups absorb this radiation at specific wavelengths. The functional groups can be determined by studying the absorbance patterns of a compound. Infrared region is between the visible region and the micro waves of the electromagnetic spectrum. It consists of longer wavelengths and lower frequency. Most common example of infrared is the thermal radiation emitted by matter near room temperature. The most common technique involving infrared is absorption spectroscopy. Chemicals can be identified and studied with this. The most common instrument used is called Fourier transf...

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... the vibrations should be equal to the frequency of the IR in order for the radiation to be absorbed. That would modify the amplitude of the molecular vibrations.
IR radiations results in molecular rotations, vibrations and vibrational coupling. Molecular rotations do not give much information. The spectra of gases are a line spectrum where as in liquids and solids a continuum spectrum is seen due to the vibration and interactions. Molecular vibrations are of two types, stretching and bending and they do not hold the atoms at a fixed place. When the vibrations interact together due to the bond being joined by a common atom, they result in coupling. Bending coupling is because of a common bond between two atoms. Maximum coupling could be observed if groups involved have an equal energy. If two or more bonds are present in between groups then couple is not possible.

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