Wait a second!
More handpicked essays just for you.
More handpicked essays just for you.
Polymers essay
Polymers essay
Don’t take our word for it - see why 10 million students trust us with their essay needs.
Recommended: Polymers essay
Polymer Structure
Although the fundamental property of bulk polymers is the degree of polymerization, the physical structure of the chain is also an important factor that determines the macroscopic properties.
The terms configuration and conformation are used to describe the geometric structure of a polymer and are often confused. Configuration refers to the order that is determined by chemical bonds. The configuration of a polymer cannot be altered unless chemical bonds are broken and reformed. Conformation refers to order that arises from the rotation of molecules about the single bonds. These two structures are studied below.
Configuration
The two types of polymer configurations are cis and trans. These structures can not be changed by physical means (e.g. rotation). The cis configuration arises when substituent groups are on the same side of a carbon-carbon double bond. Trans refers to the substituents on opposite sides of the double bond. Stereoregularity is the term used to
…show more content…
Nylon is an alternating copolymer with 2 monomers, a 6 carbon diacid and a 6 carbon diamine. The following picture shows one monomer of the diacid combined with one monomer of the diamine: Cross-Linking
In addition to the bonds which hold monomers together in a polymer chain, many polymers form bonds between neighboring chains. These bonds can be formed directly between the neighboring chains, or two chains may bond to a third common molecule. Though not as strong or rigid as the bonds within the chain, these cross-links have an important effect on the polymer. Polymers with a high enough degree of cross-linking have "memory." When the polymer is stretched, the cross-links prevent the individual chains from sliding past each other. The chains may straighten out, but once the stress is removed they return to their original position and the object returns to its original
spaced –CONH– amide groups. Nylon 6-6, or poly(hexamethylneadipamide), is composed of. two structural monomers (hexamethylendiamine (H2N(CH2)6NH2) and adipic acid. (HOOC(CH2)4COOH), whereas Nylon 6, or poly(6-caprolactam), is composed of a single structural unit (either 6-aminocaproic acid (H2N(CH2)4COOH) or caprolactam). Ultimately, the answer is yes.
The purpose of this experiment was to create a polymer by reacting a mixture of decanedioyl dichloride and dichloromethane with a mixture of water, 1,6-hexadiamine and sodium carbonate. Specifically, we created the polymer Nylon-6,10. Nylon-6,10 polymers are used in a vast majority of things we use in everyday life such as zippers, the bristles in brushes, and even car parts. This experiment was different from the industrial method of making nylon because that takes place at a much higher temperature. A polymer is a substance that has a structure made of similar or identical units bonded together. All polymerizations fall into two categories: step-growth and chain-growth (both of which we used to form our polymer). Step growth polymerization
The first term that I noted during the movie was Conductive Polymers. Conductive polymers are almost always organic meaning a large class of chemical compounds whose molecules contain carbon. These polymers have extended delocalized bonds which are bonds found in a molecule that do not belong to a single atom or covalent bond. They are conjugated systems of double bonds and in a aromatic systems. The conjugated systems are atoms covalently bonded with alternating single and double bonds. When the electrons are removed or added into the valence bands the electrical conductivity increases. The conductive polymer has a low conductivity until the electron is removed from the valence band called (p-doping) or (n-doping) until it becomes more conductive. The movement of the charges is what is responsible for electrical conductivity. These polymers are plastic which are organic polymers and with mechanical properties such as flexibility and elasticity.
Have you ever wondered why the plastic bag that you left on the porch during winter cracks or breaks more easily than when you left it during summer time but a piece of wood which was left just like the plastic bag has no effect whatsoever? This is because of a phenomenon, which only happens to polymers, known as the glass transition. For each polymer, there is a certain temperature at which the amorphous polymers undergo a second order phase transition from a rubbery and viscous amorphous solid to a brittle and glassy amorphous solid called the glass transition temperature, Tg.1 When the polymer, or in this case, the plastic bag, is cooled below their glass transition temperature, it becomes hard and brittle like a glass but when it is used above their glass transition temperatures, it might have a different effect than when used at room temperature or below the glass transition temperature as normally, different types of polymers like clothes, food packaging, insulations for wires, etc. are either used above their glass transition temperatures or
The Cherokee War could've had a different result, with minor flaws. The Cherokee war prevention was possible, however, many flaws created different results, whether benefiting the Cherokees or white settlers. According to The Effect of the Seven year’s war on the Cherokee Nation by Tyler Boulwar states, “Region is particularly emphasized since, for much of the colonial period, the Lower, Middle, Valley, Out, and Overhill Cherokees encountered varying geopolitical circumstances, situated as they were on the different frontiers of Cherokee country, and accordingly safeguarded their own interests by pursuing diplomatic, military, and economic agendas that could often be at variance. ”This shows how their geopolitical circumstances were different
Kevlar fiber is therefore a “Polyaromatic amide”, as it has a high breaking strength. Polymer chains are long, individual chains, although they behave as if they are attached to each other. The individual chains are actually held together by ‘Electrostatic Forces’ between molecules, also known as ‘Hydrogen Bonds’. Scientists discovered this, by using a special type of X-ray microscopy called ‘XANES’. This was able to reveal the orientation of molecules in materials.
This maximises the intermolecular forces between the chains as they are able to pack closely together. However, this reduces the flexibility and is therefore quite rigid and strong. This isotactic polyvinyl chloride structure occurs very little. Another structure that is produced very little is the syndiotactic PVC. The syndiotactic PVC has a regular arrangement and has similar properties of flexibility, rigidity and strength to the isotactic PVC as shown in Figure #.
There are two popular ways of creating nylon for fiber applications. One, ¡°molecules with an acid (COOH) group on each end are reacted with molecules containing amine (NH©ü) groups on each end.¡± The nylon 6,6 is made in this fashion. The other common way of making nylon fibers is by polymerizing a compound containing an amine at one end and an acid at the other, to form a chain with reoccurring groups of (-NH-[CH©ü]n-CO-)x. If the x=5, the fiber is named nylon 6 (Nylon Fiber).
chains instead of hydrogen atoms. Cross-linking is another way in which the polymer can be made stronger. This involves ultraviolet radiation that bombards the polymer with electrons and formulates bonds between the molecular chains of the polymers. This is like linear polyethylene but different in that it is more impact resistant, and it has a much higher density. This allows it to be stored or be used with different chemicals that would normally cause the polymer to desolve.3 This can start to become a problem because as the polymer continues to become chemically enhanced. So the ways of dissolving and recycling the polymer become more difficult.
There are four main levels of a protein, which make up its native conformation. The first level, primary structure, is just the basic order of all the amino acids. The amino acids are held together by strong peptide bonds. The next level of protein organization is the secondary structure. This is where the primary structure is repeated folded so that it takes up less space. There are two types of folding, the first of which is beta-pleated sheets, where the primary structure would resemble continuous spikes forming a horizontal strip. The seco...
These act randomly on all the links in the chain, reducing molecular dimensions and viscosity
There are other types of plastic piping. One other type is called CPVC which stands for chlorinated polyvinyl chloride. This type of pipe can withstand temperatures up to 180 degrees. Another type is PEX which stands for cross-linked polyethylene or XLPEl but, PEX is much easier to remember and say. This pipe can also withstand temperatures of 180 degrees.
My main aim during my undergraduate studies was to get an overview of the various fields in chemical engineering and identify a field of interest in which I could pursue my research career. Because of their vast applications, Materials & Polymer Sciences, in general, have attracted m...
However, the OVPOSS bulks were crushed to small particles with size of tens nanometers after the crosslinking process. It was noticed that the breakdown of micron-sized OVPOSS crystals to nano-sized particles was not due to high temperatures but related to the crosslinking process, because no change was seen in the morphology and size of the OVPOSS bulks in the sample P-1PO (without DCP) due to heating process. Melt mixing reaction resulted in in uniform dispersion of OVPOSS molecules in the obtained composition although there are still much slightly bulks with the size of micrometers and the crystals in the polymer matrix. The pores of the matrix are not seen in the micrograph of this blend implying that the role of DCP is often in activating the double bonds of OVPOSS