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Effect temperature has on rate of reaction experiment results
Iodine clock reaction research paper
Effect temperature has on rate of reaction experiment results
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Discussion The hypothesis was partially supported, with the first part of the hypothesis supported by the data found. The second part of the hypothesis was not supported. As seen clearly in graph 1 and 2, there is an obvious trend which shows that as the concentration of the reagents increases, the time taken for the reaction to occur decreased. Furthermore, through analysis of results it can be seen how in graph 5 and 6, the rate of the reaction can clearly be seen increasing with the concentration. Using the data which has been found, the rate law calculations have been used to form a general rate law for the landolt iodine clock reaction. It was found that the landolt iodine clock reaction is a fourth order reaction. This shows how the …show more content…
The design used in this expiriment was simple and straight forward. One fundamental design flaw was the prevalent error of human error in the measuring of the time taken for the reaction to occur. It occurred multiple times where data had to be not included because the stopwatch had not been started or stopped. Human error also effected the measuring of the chemicals used in the experiments, due to convenience measuring cylinders were used instead of electronic pipettes. This decreases the accuracy of the measured chemicals, as parallax error would of occurred multiple times. Secondly all dilutions were made by hand, not included into the raw data was a multitude of errors which occurred when the dilution was prepared wrong. Potentially the dilutions were prepared correctly, and rather the solutions were not uniform in nature. For example the way the dilution occurred was if the required molarity was 0.05 of A and the supplied was 0.2 molar of A. 10 ml of A could be taken and 10 ml of water could be added, to make a 20 ml 0.1 molar solution of A. Next take 10 ml of the new solution and add 10 ml of water, and the 0.05 molar solution of A is formed. The flaw is thought to be in the third part of the procedure, as 0.1 molar of A is thought to have been taken out of the second solution but rather the 0.2 molar has not been correctly mixed through, and as such the final molarity is not what was calculated. This effects all the data found as the majority of points found used dilution which potentially were not correctly performed. This could also potentially explain the anomalies which occurs in graph 7 at 60 degrees. A major flaw of the expiriment occurred when studying the effect of temperature, due to restrictions on time and equipment, only one of the reagents in the reaction was heated up. This was a major flaw and as such has rendered
The purpose for this experiment was to determine why it was not possible to obtain a high percent yield when Calcium Nitrate Ca(〖NO_3)〗_2 with a concentration of 0.101 M was mixed with Potassium Iodate KIO_3 with concentration of 0.100 M at varying volumes yielding Calcium Iodate precipitate and Potassium Nitrate. Filtration was used to filter the precipitates of the solutions. The percent yield for solution 1 was 87.7%, and the percent yield for solution 2 was 70.8%. It was not possible to obtain a high percent yield because Calcium Iodate is not completely soluble and some of the precipitates might have been rinsed back to the filtrates when ethanol was used to remove water molecules in the precipitate.
However, only experiments IV “Effect of Copper Metal” and V “Effect of Temperature” had reasonable results, so copper metal and temperature are the more effective factors. The less effective factors are the changes in concentrations of "H" ^"+" ions and "C" _"2" "O" _"4" "H" _"2" particles. This observation is represented in experiments II “Effect of "H" ^"+ " Ions” and III “Effect of "C" _"2" "O" _"4" "H" _"2" Concentration.” Both runs 2B and 2C had the fastest times of 25 seconds and 86 seconds
Random errors reflect a low precision through high scatter. Increasing the sample size of the number of tablets used will produce more data that can be graphed, and from which a more reliable and representative line of best fit could be produced, ultimately minimising random errors. Additionally, increasing the number of trials for each number of reacting Alka Seltzer tablets would minimise random errors by helping to produce a more precise average change in mass. Modifying the method can also help minimise the effect of random errors, by obtaining more reliable results. For example, instead of cutting the Alka Seltzer tablets in half, whole Alka Seltzer tablets could have been used, and the amount of reacting HCl could have been increased to account for the increase in the number of tablets used for each ample. In doing this, the mass of the reacting Alka Seltzer tablets will be more consistent for each trial, and the state of subdivision of the tablets could be truly kept
This would give us an extra measure of accuracy each time. Another way to improve the experiment and to produce consistent readings was to used distilled water. This is because the distilled water contains no impurities and therefore no hardness in water.
The rate law determines how the speed of a reaction occurs, thus allowing the study of the overall mechanism formation in reactions. In the general form of the rate law, it is A + B C or r=k[A]x[B]y. The rate of reaction can be affected by the concentrations such as A and B in the previous equation, order of reactions, and the rate constant with each species in an overall chemical reaction. As a result, the rate law must be determined experimentally. In general, in a multi-step reaction, there will be one reaction that is slower than the others.
Going into details of the article, I realized that the necessary information needed to evaluate the experimental procedures were not included. However, when conducting an experiment, the independent and dependent variable are to be studied before giving a final conclusion.
One possible source of experimental error could be not having a solid measurement of magnesium hydroxide nor citric acid. This is because we were told to measure out between 5.6g-5.8g for magnesium hydroxide and 14g-21g for citric acid. If accuracy measures how closely a measured value is to the accepted value and or true value, then accuracy may not have been an aspect that was achieved in this lab. Therefore, not having a solid precise measurement and accurate measurement was another source of experimental error.
Planning Firstly here is a list of equipment I used. Boiling tubes Weighing scales Knife Paper towels 100% solution 0% solution (distilled water) measuring beakers potato chips Cork borer. We planned to start our experiment by doing some preliminary work. We planned to set up our experiment in the following way.
The rate equation is in terms of concentration over time and the reaction rate compares the increase/decrease
Many steps were taken it minimize error, but error may have altered results regardless. Starting at the beginning of the experiment, one place that error could have occurred was in the recording of data. There were numerous places that this could have happened, such as when taking the mass of the double salts or when taking the mass of the crucible and lid. Further on in the experiment, there was a chance of error when trying to extract the last bit of barium sulfate from its beaker into the funnel. Also mass could have been lost on the glass stirring rod.
The aim of this experiment was to investigate the affect of the use of a catalyst and temperature on the rate of reaction while keeping all the other factors that affect the reaction rate constant.
Firstly, we need to keep the chemical at a constant concentration. So, in this experiment we have chosen to keep hydrochloric acid at a constant concentration (5cm3). We could have, however, used Sodium Thiosulphate as a constant, but we had chosen to use Hydrochloric acid. Next, we must make sure that the solution is kept at a constant volume throughout the experiment. If the volume is different, then it could give different results if it was at a constant volume.
Looking at the table of results above and the graph, it is shown that the higher the temperature got, the shorter the reaction time. The obtained results have been plotted on a line graph of the temperature of hydrochloric acid (y-axis) against reaction time (x-axis). This line graph in fig.2 also clearly shows that as the temperature increases, so does the speed of the reaction, shown by a reduction in the time taken. This corroborates the collision theory, where as the temperature of particles increase, the particles gain more kinetic energy and react with each other upon collision. This is shown as to happen in the hydrochloric acid, where the hydrochloric acid particles collide more with the particles of the magnesium ribbon as the temperature was increased. The above graph shows a gradual sloping curve, which gets steeper at higher temperatures. This shows that the reaction will reach a peak rate of activity as the gaps between the temperature and reaction times continue to decrease. The experiment fulfills the aim and clearly shows that as the temperature of a reaction is increased so does it’s rate of reaction, proving the hypothesis to be correct.
Most reactions such as this come under the category of the Landolt Clock Reaction. There are several factors which affect the rate of a clock reaction such as temperature, concentration, particle size and catalysts. The reaction depends on the speed the chemicals collide with each other. “Collision theory states that the rate of a chemical reaction is proportional to the number of
There is also the potential of human error within this experiment for example finding the meniscus is important to get an accurate amount using the graduated pipettes and burettes. There is a possibility that at one point in the experiment a chemical was measured inaccurately affecting the results. To resolve this, the experiment should have been repeated three times.