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Law of thermodynamics
Law of thermodynamics
1st law of thermodynamics and thermochemistry
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dwell on the factors that preclude the attainment of ideal-performance of the system. Analysis based on the combined first and second law of thermodynamics commonly known as availability analysis or exergy analysis is particularly suited for achieving more efficient resource use since it enables the locations, types and true magnitudes of waste and loss to be determined. This information is quite helpful for the design of thermal systems, for directing the efforts to reduce the sources of inefficiency in the existing systems and evaluate system economics. [1, 2 & 3].
In thermodynamics, exergy is defined as the maximum theoretical work which can be obtained as the system comes to equilibrium with its reference environment. Unlike energy, exergy
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The magnitude of exergy destruction is a quantitative measure of irreversibilities present in the system. Thus, the knowledge of the magnitude of exergy destruction and identification of the component where maximum exergy destruction occurs can be helpful in the better design of the equipment and selection of appropriate processes for minimizing losses.
Flynn et al. [4] studied a turbocharged, intercooled diesel engine using second law analysis to evaluate low-heat-rejection engine concepts. They were performed the simulation of engine cycle process. Primus and Flynn [5] reported a study demonstrating the benefits of using the second law in determining various energy losses in a diesel engine. Defining a thermodynamic system as outside the engine cylinder. Alkidas [6] applied energy and exergy balances to a diesel engine using experimental measurements. Shapiro and Van Gerpen [7] extended their earlier work to include a two-zone combustion model and applied this model to both a compression-ignition and a spark ignition engine. As before, their study included chemical exergy considerations. They presented the
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Van Gerpen and Shapiro [10] performed a second law analysis of diesel engine combustion employing a standard cycle simulation Rakopoulos et al. [11] investigated the accumulation and destruction of exergy in a direct-injection diesel engine based on experimental data. Rakopoulos et al. [12] analyzed the multi-cylinder turbocharged diesel engine from a second law perspective, considering single zone thermodynamic model for combustion process. A comprehensive computer software was developed to simulate various process. Datta and Som [13] developed a theoretical model for exergy analysis, based on availability transfer and flow availability, in the process of spray combustion, to evaluate the total thermodynamic irreversibility. Caton [14] reviewed over two dozen previous studies that had investigated the operation of internal combustion engines using the second law of thermodynamics. C.D. Rakopoulos and D.C. Kyritsis [15] applied the first and second law analysis is used to calculate the rate of entropy production as a function of fuel reaction rate. In the modelling of engine, a three-hole
8. If a coal-burning electrical generating plant burns 2 tons of coal to generate 6000 kWh of electricity, calculate the efficiency of the plant as the ratio of electricity output to fuel energy input (refer to Table 3.4).
Driven in large part by global initiatives and the potential for stringent regulations, the past decade or two has seen a marked increase in the importance of improvements with respect to environmental standards, including emissions and increases in fuel economy. In 2002, Cummins Emissions Solutions was launched after the need was identified for an emission solution that would help engines meet future regulations. In 2006, Cummins pioneered a hybrid diesel-electric bus which reduced fuel consumption and greenhouse gasses by more than 30 percent and me...
The diesel engines combustion process is a little different than the typical gasoline engine. A couple main things that diesel engines have that gasoline engines do not are, carburetors and spark plugs. Unlike a gasoline engine, air is first allowed into the cylinder rather than a fuel and air mixture. Once the air is compressed it creates a source of heat, then a mist of fuel is injected to start the combustion process which then creates the energy. Since diesel engines do not have spark plugs they are able to take in larger amount of fuel, this obviously means there will be more power and will guarantee better efficiency. Another thing that is very important is that diesel tends to be a better lubricant than gasoline, being that it is a better lubricant there will be less friction which will generally increase the life of the engine (Woodford). Diesel engines operate at slower speeds than gasoline engines, therefore diesel engines tend to have longer lifespans than gasoline
Determination of the Enthalpy Change of a Reaction. Determine the enthalpy change of the thermal decomposition of calcium carbonate by an indirect method based on Hess' law. Determination of the Enthalpy Change of a Reaction. Determine the enthalpy change of the thermal decomposition of calcium carbonate by an indirect method based on Hess' law. Using the proposed method of obtaining results, these values were gathered.
be yes as I will then be able to use enthalpy change of reaction to
85% equipments use single-cylinder diesel engines, while the rest use multi-cylinder ones. In the market of multi-cylinder diesel the competition is less intense because of excessive demand. The prospect is much more promising. Longxi has a certain competitive advantage in this market, resulting from its popular product such as SL2100.
Life-Cycle Costing Manual for the Federal Energy Management Program by Sieglinde Fuller and S.R. Petersen. NIST Handbook 135. National Institute of Standards and Technology, 1995.
The pinch analysis uses Temperature-Enthalpy (T-H) diagram, the composite curves. the temperature axis represents the available driving forces for heat transfer, while the enthalpy axis shows the supply and demand of heat. For processes with multiple cold streams, the individual process thermal duties can be combined into a single “cold composite curve” drawn on a Temperature-Enthalpy T-H diagram, which represents the enthalpy demand profile of the process. Similarly, all the thermal duties for hot streams can be combined into a single “hot composite curve”, which represents the enthalpy availability profile of the process.
There are two main kinds of problems in internal combustion engine which contribute negatively in our life. These two problems are the emissions, which is related to the environment, and mechanical problems, which are related to the internal combustion engines themselves. In this project, the focus will be on some solutions for these two problems.
Energy can come in many different ways but not every way is good for the environment. By-products produced from the waste or energy being converted can cause harmful repercussions to the environment. There is more than 200 million tons of hazardous waste that is created annually through such things like pharmaceuticals, cosmetics, cleaning products, etc. (High Temperature Incineration, n.d.). I will be discussing the incineration process as well as the pros and cons of incineration based waste to energy have on the environment. I will also be going over my views on incinerating waste and what steps should be taken to get rid of waste more effectively. To better understand the positives and negatives about incineration technology the process
In today’s society, cars and other transportation vehicles produce pollution, harming the environment as well as one’s health. Engines produce toxic substances such as nitrogen oxides and sulfur dioxide. However, the invention of the catalytic converter has helped reduce the pollution. Catalytic converters were first used due to the contractions on toxic emission regulations in the 1970s. The catalytic converter “turn the harmful chemicals in vehicle exhausts into harmless gases such as steam” (Woodford). These catalytic converters are essential to creating a less polluted atmosphere. An engine with and without a catalytic converter differs greatly and the reactions occurring are very significant in understanding the role of the converter;
The internal combustion engine has become an integral part of the lives of every person on earth. They’re the devices that have allowed us to cross continents reliably, generate electricity in remote areas and fly around the world in a matter of hours. All these engines do is burn fuel and convert its energy into work. It’s these heat engines that have really changed the world. However the convenience they bring has come at a great cost. The major problem with the internal combustion engine is the environmental damage it has caused. It is only now we are beginning to realise the full extent of this damage.
Thermodynamics is the branch of science concerned with the nature of heat and its conversion to any form of energy. In thermodynamics, both the thermodynamic system and its environment are considered. A thermodynamic system, in general, is defined by its volume, pressure, temperature, and chemical make-up. In general, the environment will contain heat sources with unlimited heat capacity, allowing it to give and receive heat without changing its temperature. Whenever the conditions change, the thermodynamic system will respond by changing its state; the temperature, volume, pressure, or chemical make-up will adjust accordingly in order to reach its original state of equilibrium.
Ohman and Lundqvist: using low temperature heat sources they adopted local Carnot efficiency, which corresponds to efficiency of each Carnot cycle in sequential systems, and analyzed several power cycles with published field data.
In my undergraduate years, I have acquired a strong background in the fundamentals of basic mechanical engineering, having studied subjects such as Strength of Materials, Thermodynamics, Fluid Mechanics, Heat and Mass Transfer, Design of Machine Elements and Automobile Engineering. Whilst pursuing my diploma & degree courses, my interest for Automotive Engineering grew even more having learnt more on the different types of internal combustion engines, their configuration and importance. However, what I lacked was a practical understanding on these core areas of Automotive Engineering. To gain a better understandi...