The Importance of Sphingomyeline

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The main lipids components of the cell membrane are the sphingolipids, cholesterol, and other phospholipids. The most predominant element of the sphingolipid molecule in the cell membrane is sphingomyelin, which is composed of a hydrophilic phosphorylcholine headgroup and a highly hydrophobic ceramide molecule. The ceramide group in sphingomyelin composed from amide ester of the sphingoid base D-erythro-sphingosine and a fatty acid of C16–C26 chain length. The lateral association of sphingolipids and cholesterol promoted by a strong interaction between the cholesterol sterol ring structure and the ceramide molecule of sphingomyelin, which are facilitated by hydrogen bonds and hydrophobic van der Waal interactions in addition to hydrophilic interactions and thus the split-up from other phospholipids into distinct microdomains (Brown & London, 1998). These microdomains have been termed rafts that play a function in aggregation of receptor molecules and the reorganization of intracellular signaling molecules to transmit a signal into the cell.

Sphingomyeline (SM) seems to be the main sphingolipid source for bioactive ceramide in the vast majority of cells, thereby stressing the major functions for ASMs in initiating ceramide signaling (Perrotta et al., 2010). ASM was initially recognized as a cation-independent hydrolase involved in the catabolism of SM in lysosomes (Horinouchi et al., 1995).Now there are two types of acid sphingomylinase. First is the lysosomal acid sphingomylinase(L-ASM) which has a major role in the production of ceramide as a response of the cell to stress such as infection, environmental insults, ligation of death receptors, and exposure to chemotherapy drugs. The transferring L-ASM to the lysosome is vi...

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...it is most obvious in endothelial cells. Probably, the absence of functional ASM inhibits the production of ceramide and reorganization of membrane rafts into platforms, protecting against cell death.

By introducing a partially functional SMPD1 gene onto the complete knockout (ASMKO) background, a transgenic mouse model of type B NPD has been produced, This results in a mouse with ~ 8 % residual ASM activity in most organs (Marathe et al., 2000 ). Notably, these mice never develop a neurological phenotype and live a normal lifespan. Nevertheless, by ~8–10 months of age they begin to show lipid storage in RES organs. These interpretations provide in vivo evidence that low levels of ASM activity in the brain are likely to prevent neurological disease in ASM patients, and have important applications for the treatment of neurological (type A )ASM-deficient NPD.

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