Laser-Induced Breakdown Spectroscopy

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Introduction

When analyzing physical evidence, there are many different approaches available for forensic analysis. However, it should be noted that no single method or technique yields satisfactory results. Often, the item of forensic interest may require the use of multiple instruments. There is a growing need for advancement for new forensic tools, one that will optimize analytical figures of merit along with many other principal factors such as cost efficiency (cost per analysis), ease of use, instrumentation portability, time for sample preparation, sample consumption, and throughput [5]. In a typical crime scene, analysts analyze numerous trace evidence samples that require determination of their elemental composition. However, …show more content…

It has been successfully applied to the elemental analysis of various materials, including those of forensic interests [5]. Its growing attraction is due to its high sensitivity, rapid results, and virtually micro-destructive features, just to name a few. Its versatility and low-cost adaptation of atomic emission spectroscopy, has been utilized effectively to the forensic analysis of counterfeit currency, drugs, explosives, fingerprints, ink and paper, glass, gunshot residue, and many other items of specific forensic interests. The method requires little to no sample preparation and can simultaneously provide information on major, minor and trace element compositions [5]. LIBS also has the potential to be used in real time on the field for direct or stand-off analysis. The instrumentation needed is reasonably simple, very robust, and is also available in a compact format the enables portable …show more content…

The plasma consists of electronically excited atoms and ions, which can then be analyzed by the spectrometer. When the laser pulse terminates, the plasma begins to cool [11]. It is during this cooling process, where the electrons of the atoms and ions at the excited states decay back into their natural ground states, causing the plasma to emit characteristic wavelengths of light. The atomic emissions can be detected approximately 1 μs after the initial pulse. The emitted light from the plasma is collected by the spectrometer coupled with either a CCD or ICCD spectrograph detector module for the LIBS spectral analysis [11]. Each element correlates to a unique LIBS spectral peaks. Thus, by identifying the different peaks of the analyzed sample, its chemical composition can be rapidly

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