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Representation of ice-based energy storage technologies
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Latent Heat
Latent heat thermal storage is an alternative to the sensible heat system. This system operates by making use of the ability of the material to store energy through its ability to phase change from solid to liquid or liquid to solid. (Sharma, Tyagi, Chen, & Buddhi, 2009). The process relies on the chemical properties of the chosen material where heat is absorbed or release as the material undergoes a phase change from solid to liquid or vice versa. (Sharma, Tyagi, Chen, & Buddhi, 2009). The process starts when the temperature reaches the required temperature-phase change temperature- and stays constant until the whole process change is finished. Most of the latent heat thermal storage systems are currently based on solid to liquid transition.
The graph below shows the heat storage for a latent heat system in the case of a solid-liquid change.
Figure 1: heat storage as latent heat for a solid-liquid phase change (Mehling & Cabeza, 2008)
The thermal storage capacity of a latent heat system for the case of material undergoing a solid-liquid phase change can be seen below (Portaspana, 2011):
Q= ∫_(T_i)^(T_m)▒〖m. C_p dT+ m.∝_m.∆h_m+∫_(T_m)^(T_f)▒〖m.C_p.dT〗〗
A latent heat system has two main advantages over a sensible system:
It allows large amount of energy to be stored with only small changes in temperature thus allowing the system to have a high storage density.
The phase change process occurs over a long period with allows any temperature change to be controlled properly.
Ice based technology
Ice based technology also known as ice storage air conditioning is the process of using ice to store energy. This method is used in order to decrease the energy usage cost by transferring the energy consumption from high ...
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...o turn it back into a high pressure gas. The gas is then used to turn a turbine and a generator to produce electricity (Liquid Air Energy Netwrok, 2012).
Below is a representation of how the cryogenic energy storage operates.
Figure 4: representation of cryogenic energy storage system (Highview power storage, 2011)
A pilot plan was set up in Slough, United Kingdom with the aim of producing 300kW by using the liquid air cycle. The results obtained were promising with a process efficiency of 50-60% being achieved through the recycling of thermal energy produced during power recover process (University of Birmingham, 2013). The system may still lag behind in terms of efficiency if compared to some batteries but it possesses the advantage of having an almost unlimited amount of charge and discharge cycle without any loss in storage capacity (Lombardo, 2013).
Water is heated in the first container (1) which produces steam. The steam carries heat, called latent heat. A pump on the wall of the first container (1) pumps the steam into the second container (2). The steam from the first container (1) heats the syrup and boils it, creating sugar crystals, in the second container (2), using up the latent heat in the steam from the first container (1). The evaporating syrup creates it's own steam, with latent heat as well. A pump on the opposite wall of the second container, (2), pumps the latent heat in the steam into the third container (3).
Matter exists in three basic states: solid, liquid, or gas. A substance experiences a phase change when the physical characteristics of that substance change from one state to another state. Perhaps the most recognizable examples of phase changes are those changes from a solid to a liquid or a liquid to a gas. When a substance goes through a phase change, there is a change in the internal energy of the substance but not the temperature of the substance (Serway, et al. 611).
Introduction: A phase change is a result from the kinetic energy (heat) either decreasing or increasing to change the state of matter (i.e. water, liquid, or gas.) Thus saying, freezing is the phase change from a liquid to a solid which results from less kinetic energy/heat. Also, melting is the phase change from a solid to a liquid which results from adding kinetic energy/heat. So, the freezing and melting point of something is the temperature at which these phase changes occur. Therefore, a phase change will occur when a vial of 10 mL of water is placed into a cup of crushed ice mixed with four spoonfuls with 5 mL of sodium chloride for 30 minutes. If 10 mL of water is placed in an ice bath, it will then freeze at 5 degrees Celsius because the kinetic energy will leave quicker with the ice involved. The purpose of this lab is to observe what temperature the water must be to undergo a phase change.
on how long it takes to heat up. If we heat a large volume of water it
good emitter of heat radiation so a lot of heat will be lost to the
Specific heat capacity of aqueous solution (taken as water = 4.18 J.g-1.K-1). T = Temperature change (oK). We can thus determine the enthalpy changes of reaction 1 and reaction 2 using the mean (14) of the data obtained. Reaction 1: H = 50 x 4.18 x -2.12.
The objective of this experiment was to identify a metal based on its specific heat using calorimetry. The unknown metals specific heat was measured in two different settings, room temperature water and cold water. Using two different temperatures of water would prove that the specific heat remained constant. The heated metal was placed into the two different water temperatures during two separate trials, and then the measurements were recorded. Through the measurements taken and plugged into the equation, two specific heats were found. Taking the two specific heats and averaging them, it was then that
Process bc : This high pressure and high temperature vapour then enters a condenser where the temperature of the vapour first drops to saturation temperature and subsequently the vapour refrigerant condenses to liquid state .
Refrigeration Refrigeration is defined as “The process of removing heat from an enclosed space, or from a substance, to lower its pressure.” (First website given in bibliography) In simpler terms, it is removing heat from states of matter in order to keep them cooler. The basic need for refrigeration is to cool food and beverages, as they often get spoilt if the temperature is high. Before actual refrigerators and other such mechanical systems were introduced, it was very common for people to cool their food with ice and snow.
The term phase transitionxis most commonly used to describe transitions between solid, liquid and gaseous states of matter, and, in rare cases, plasma. A phase of a thermodynamic system and the states of matter have uniform physical properties. During a phase transition of a given medium certain properties of the medium change, often discontinuously, as axresult of the change of some externalxcondition, such asxtemperature, pressure, or others. For example, a liquid may become gas upon heating to the boilingxpoint, resulting in an abrupt change inxvolume. The measurement of the external conditions at which the transformation occurs is termed the phase transition. Phase transitions are common in nature and used today in many technologies.
Heat energy is transferred through three ways- conduction, convection and radiation. All three are able to transfer heat from one place to another based off of different principles however, are all three are connected by the physics of heat. Let’s start with heat- what exactly is heat? We can understand heat by knowing that “heat is a thermal energy that flows from the warmer areas to the cooler areas, and the thermal energy is the total of all kinetic energies within a given system.” (Soffar, 2015) Now, we can explore the means to which heat is transferred and how each of them occurs. Heat is transferred through conduction at the molecular level and in simple terms, the transfers occurs through physical contact. In conduction, “the substance
Another necessity of refrigeration is in the developing of certain scientific equipment and their operation under controlled environment to get reliable results. Many industries like chemical, milk dairy, oil refinery, etc. require low temperature to carry various processes.
The temperature is then reduced slightly and maintained at the simmering point where the liquid is just moving.
In summary, the rate of cooling from the austenite phase is the main determinant of final structure and properties.