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Chemical engineering
Chemical engineering
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Fractionation Unit
Purpose of the Unit
The Fractionation Unit supplies ethane and propane, at the required purity, as make up to the refrigeration cycles. In addition, methane is sent to the HP fuel gas system and pentane to the LP fuel gas system. NGLs are re-injected into the LNG product and hydrocarbon condensate is produced to the required vapour pressure and directed to storage.
Process Introduction
The Fractionation Unit consists of four fractionation columns in series:
• a De-methaniser
• a De-ethaniser
• a De-propaniser
• a De-butaniser
The unit is closely integrated with the scrub section in order to achieve optimum cold economy and a minimum processing/recycle of 'excess' components. Any excess light components removed
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The two-phase feed at -20C and 30 bara, which contains considerable levels of methane and nitrogen, is routed to the top of the column. The falling liquid is then stripped of methane and nitrogen by rising vapour produced, by exchange with Heat transfer fluid (HTF), in a De-methaniser Reboiler. The methane and nitrogen have to be removed to allow proper recovery of ethane in the downstream De-ethaniser column.
The De-methaniser column overheads are mixed with Natural Gas Liquids (NGLs) from the other three fractionation columns in an NGL collection header, cooled against low pressure propane in a heat exchanger from 15C to -29C, and separated in a Natural Gas Liquid Re-injection
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Vapour from the top of the De-ethaniser column is condensed against medium pressure propane in an overheads condenser before passing into a reflux drum. From the reflux drum ethane refrigerant make up, in vapour form, is supplied to the Liquefaction Unit and ethane liquid is pumped back to the column as reflux or to the Refrigerant Storage Unit for refrigerant make up purposes as required. The bottoms from the De-ethaniser Column, at 128C and 27 bara, are fed to the De-propaniser Column through a level control valve. Flashing across the valve reduces the pressure to 16 bara at
hydrocarbons that forms during the extraction of natural gas and is used as a thinning
Norbert Rillieux invented the triple effect vacuum evaporator. The "triple effect" is for the multiple things that the system does all at the same time. The "vacuum" is for the vacuum of air that is used in the system, and the "evaporator" is for the sugarcane liquid syrup that is heated and evaporated into regular sugar. The actual system is somewhat complicated, so please see the picture that is provided.
The procedure for this laboratory assignment is on the following pages. 3) Separation of Carboxylic Acid, Phenol and Neutral Substance. The purpose of this acid/base extraction is to separate a mixture of equal parts of benzoic acid(strong acid) and 2-naphthanol(weak base) and 1,4- dimethoxybenzene(neutral) by extracting from tert-butylmethyl ether(very volatile).The goal of this experiment was to identify the three components in the mixture and to determine the percent recovery of each from the mixture. 4) Separation of a Neutral and Basic Substance. A mixture of equal parts of a neutral substance containing either naphthalene or benzoin and a basic substance containing either 4-chloroaniline or ethyl 4-aminobenzoate were to be separated by extraction from an ether solution. Once the separation took place, and crystallization was carried out, it became possible to determine what components were in the unknown mixture, by means of a melting point determination.
As the laboratory generates waste, it is accumulated following the procedures list in this document.
The parts are collected and stored temporarily in a location called storage buffer before downstream.
Separation of olefin-paraffin mixtures resulting from cracking are often done in a series of distillation columns designed for this purpose. A common process diagram is shown in Figure 2-1. @ Master thesis). For each olefin-paraffin pair, two columns are required. The first separates that size of molecule from the rest of the mixture (e.g., separation of ethylene and ethane from the remaining feed) while the second separates the olefin-paraffin pair from each other (e.g., separation of ethylene from ethane).
This fluid is made up of 32.5% urea in 67.5% de-ionized water. This mixture is then injected into the exhaust stream using an advanced catalyst system. When DEF is released into the exhaust stream the hot exhaust causes the fluid to release ammonia which then breaks down the greenhouse harming gas of NOx into nitrogen and water. This fluid must be refilled at approximately every 10,000 miles (Voelcker).
After the oil/gas mixture is drawn from the ground, it is then stored into a storage tank and allowed to rest for a while. Then the gas is piped off to a set of distillation columns to clean up the ethane. In order to activate the chemical reaction necessary to separate the ethane, a thermal cracking unit (a sort of long heated tube) i.e. a plug flow reactor is used. After a series of distillations, ethylene exits the tube.
The Olefins II Unit makes hydrocarbons from naphtha or natural gas using furnaces. After distillation, the p...
Process cd : This liquid refrigerant is collected in the liquid storage tank and later on it is expanded to low pressure and temperature by passing it through the throttle valve. At point d we have low temperature liquid refrigerant with small amounts of vapour .
This type of turbine is mainly used to run the electric generator for the electric power production. Air at atmospheric pressure P1 and temperature T1 enters the compressor where it is compressed isentropically. During compression process, pressure and temp increased to P2 and T2. This compressed air will then enter the combustion chamber where it helps in burning the fuel. Due to burning of fuel, it is mixed with gases produced due to burning and attains a very high temp T3. This high pressure and high temperature air then runs the turbine where it is expended and hence the temp and pressure of air is reduced to T4 and P4. The turbine is coupled with generator as well as compressor. Therefore, some part of the turbine output is used to run the compressor while rest part of the turbine output is used to run the electric generator. Process 2-3 and 4-1 are isobaric process as shown in the figure 2.
... temperature of 112 0C also and a pressure 2.5 bar. Cooling water is used to condense the vapor exiting column. Remaining methane and hydrogen are separated in reflux drum where the vapor stream is combined with other gases streams. The overhead of first and second separator are combined to form fuel gas. The liquid stream exiting in the bottoms of the reflux drum is pumped at pressure of 3.3 bar for discharging pressure. The pump stream is separated in two streams. One stream is to feed to tray one of the column and the other one stream is cooled down to 38 0C in heat exchanger. Then, the cooled product stream is sent to storage.
Removal/ wasting of activated sludge during this stage if the amount of activated sludge presence in excess.
It goes through a series of heating and cooling to produce the alcohol once it is complete, it then ships to the fuel pumps, and eventually into the world’s vehicles. Then...
The reverberatory furnace’s off-gas passes through a waste heat boiler and a balloon flue before reaching final processing by means of electrostatic dust precipitation. Flue dust is recycled to the furnace where the weak concentration off-gas will be directly discharged into the atmosphere using a concrete stack. Treatment in a wet gas scrubbing plant may also be utilised. Once scrubbed, off-gas is dispersed to the atmosphere using a high clean gas stack. Heat boilers are used to generate steam which heats the primary combustion air for coal pulverisers and also directs secondary air to the furnace. Off-gas from the converters passes through electrostatic precipitators that cater for gas cleaning. A sulphuric acid plant treats the gas and concentrated sulphuric acid is manufactured for sale in the domestic