Polymerization can be divided into the two types of reactions, such as chain-growth and step-growth polymerization. Cationic polymerization is the step-growth type of polymerization. Otherwise, it is called as addition polymerization since the reaction requires addition of the substance of a certain initiator or a catalyst. In the cationic polymerization, the catalyst is cationic and it transfers the charge to the monomer in reac-tion. Cationic polymerization of biological oils occurs in presence of superacids. The re-search under consideration is going to study the process of cationic polymerization in the soybean oil with the help of the superacids as the catalyst.
This type of polymerization is not widespread in industry and therefore the mech-anism of such reaction has not been studied in detail (16). The purpose of the current re-search is to investigate how the process of cationic polymerization in the vegetable oils occurs. Soybean oil is taken as the resource for the research since it has around 4.6 double bonds / triglyceride that make it potentially polymerizable. It is suggested that the re-action under consideration may involve conjugation of double bonds in polyunsaturated fatty acids (linoleic and linolenic).
Ene reactions also supposedly may be faced in the process of reaction. The pas-sage of the ene reaction in the soybean oil is not a new phenomenon as it was reported in the experiment of Biswas et al. (23). The occurrence of the crosslinking ene reactions in the soybean oil, which was mixed with diethyl azodicarboxylate at the average room temperature, was the outcome of the experiment. It is suggested that ene reactions also can occur during the process of polymerization of the soybean oil with the superacids...
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... distinguish the properties such as weight. In the research under consideration the identification, quantification, and purifi-cation of the necessary compounds can be performed. The method is able to determine polymerized triglycerides in the vegetable oils (29) and thus it is highly beneficial for the research. Liquid chromatography is applicable in the variety of the practical spheres, such as medicine and legal study, so it has high reliability.
The discussed methods are of high value for the research’s outcome. With the combination of the analyses of different type, the process of formation of the oligomers in polymerized oils can be analyzed. The products of splitting will be analyzed during the research and the methods of linking of the triglyceride units in the polymerized oils will be studied. The conclusions will be based upon the empirical investigation.
The boiling point of the product was conducted with the silicone oil. Lastly, for each chemical test, three test tubes were prepared with 2-methylcyclohexanol, the product, and 1-decene in each test tube, and a drop of the reagent were added to test tubes. The percent yield was calculated to be 74.8% with 12.6g of the product obtained. This result showed that most of 2-methylcyclohexanol was successfully dehydrated and produced the product. The loss of the product could be due to the incomplete reaction or distillation and through washing and extraction of the product. The boiling point range resulted as 112oC to 118oC. This boiling point range revealed that it is acceptable because the literature boiling point range included possible products, which are 1-methylcyclohexene, 3-methylcyclohexene, and methylenecyclohexane, are 110 to 111oC, 104oC, and 102 to 103 oC. For the results of IR spectroscopy, 2-methylcyclocahnol showed peaks at 3300 cm-1 and 2930 cm-1, which indicated the presence of alcohol and alkane functional group. Then, the peak from the product showed the same peak at 2930 cm-1 but the absence of the other peak, which indicated the absence of the alcohol
Acid or base-catalyzed hydrolysis yields the component fatty acid, some examples of which are given in the following table, together with the alcohol component of the lipid. These long-chain carboxylic acids are generally referred to by their common names, which in most cases reflect their sources. Natural fatty acids may be saturated or unsaturated, and as the following data indicate, the saturated acids have higher melting points than unsaturated acids of corresponding size. The double bonds in the unsaturated compounds listed on the right are all cis (or
In order to determine which fish oil supplement is best for us, we must first have a greater understanding of how each constituent is molecularly structured and how it is readably absorbed into the body. Triglycerides by definition are the main constituents of animal fats and vegetable oil. TG is a chemical compound that is formed from three fatty acids and one molecule of glycerol, as seen in Figure 1: The Molecular Structure of a Triglyceride.
In part A of the lab, our group measured the effects of emulsification on the digestion of lipids in the presence of cholic acid, a purified bile salt, and distilled water. The tube containing vegetable oil and no bile began to separate into two layers within the first minute of being mixed together. Although there were no clear distinctions within the first 15 seconds, by the fifth minute, there appeared two separate layers; one resulted in a yellow appearance while the other one was clear. As expected and predicted in our hypothesis, it was easier to notice the separation of the two layers in the tube without any bile salts because lipids are hydrophobic meaning that oils are more difficult to digest. However, due to the fact that when in the presence of bile salts, lipids
The percentage yield gained was 70% from the Fischer Esterification reaction, which evaluates to be a good production of yield produced as the reaction is known to be reversible where conditions such as the concentration of the reactants, pressure and temperature could affect the extent of the reaction from performing. These white crystalline crystals were tested for impurity by conducting a melting point analysis and taking spectrospic data such as the IR spectra, HNMR and CNMR to confirm the identification of the product. These spectrospic methods and melting point analysis confirmed the white crystalline crystals were benzocaine.
The spots moved 3.8cm, 2.3cm, 2.1cm, 1.8cm, and 2.5 cm, for the methyl benzoate, crude product, mother liquor, recrystallized product, and isomeric mixture, respectively. The Rf values were determined to be.475,.2875,.2625,.225, and.3125, for the methyl benzoate, crude product, mother liquor, recrystallized product, and isomeric mixture, respectively. Electron releasing groups (ERG) activate electrophilic substitution, and make the ortho and para positions negative, and are called ortho para directors. In these reactions, the ortho and para products will be created in a much greater abundance. Electron Withdrawing groups (EWG) make the ortho and para positions positive.
The most common form of polyethylene is petroleum based or olefins based; as before mentioned polyethylene compounds have a wide commercial applicability and are made from non-renewable resources (Harding, Dennis, von Blottnitz, Harrison, & S.T.L., 2007). Its manufacturing processes are regarded as energy intensive and release significant amount of CO2 and heat into the atmosphere (Broderick, 2008). Next a little more detailed description of polyethylene’s production processes will be presented, with a focus on the way the material inputs are extracted and synthesized.
The crude extract obtained by solvent extraction was subjected to various qualitative tests to detect the presence of common chemical constituents as:
The synthesis of polymers starts with ethylene, (or ethene). Ethylene is obtained as a by-product of petrol refining from crude oil or by dehydration of ethanol. Ethylene molecules compose of two methylene units (CH2) linked together by a double carbon
Ever since I began studying science and mathematics at all levels of educations I have always had an interest in the production of useful materials. In the growing turmoil of today; a world full of global warming and diminishing resources, questions often arise in my mind such as, "can we make a more efficient, more durable and a renewable resource that will overshadow fossil fuels? and have less of an impact on our environment?" Up to now, I have not found a solution to these questions and answering these questions is a personal aspiration of mine which I aim to fulfil by achieving a degree in Chemical engineering and eventually I will contribute to the field in my own unique way. The debate surrounding sustainable energy fascinates me, having recently learned from personal research I have understood what an authoritative role chemists and chemical engineers play in the industry at the present time and how, by working as a team, they contribute to an improved future for the whole world. However, one of the main reasons that has single-mindedly driven me this far to want to study chemical engineering is a book I have read, “Beyond the Molecular Frontier: Challenges for Chemistry and Chemical Engineering” While reading this book, I had solidified my understandings of what chemical engineering is all about. Also, one of the main processes mentioned was polymerisation and is something I already study in A-level chemistry, it is something that not only interests me, but is a personal career aspiration of mine. Reading this book gave me a determination to be the person who helps improve the future of the industry and provide an answer to the questions I always ask myself by studying this degree.
Starting this experiment, we knew that the extraction was going to form varies layers due to the density differences. When placing three different substances, we saw that two layers formed because the Clove Oil is soluble in MTBE, but not in water. In order, to get the organic layer we used separatory funnel to take out the excess substances and leave the oil layer. Then we transferred to a beaker and dried with Magnesium Sulfate. Lastly, we filtered the liquid using funnel; we placed the liquid to boil, let it cool to room temperature. The purpose of drying and evaporation is to help us with the Gas Chromatography analysis of the product.
German Chemist Hans von Pechmann first synthesized Polyethylene by accident in 1898 by heating diazomethane. His colleagues characterized the waxy substance polyethylene due to the fact that they recognized that it consisted of long ethene chains. It was then first industrially synthesized by accident in 1933 by applying extremely high pressure to ethylene and benzaldehyde. Over the years, development of polyethylene has increased due to the additions of catalyst. This makes ethylene polymerization possible at lower temperatures and pressures.1
In this experiment, lipids from ground nutmeg are extracted using a combination of solvents and identify the lipids through chromatography. The purpose of using solvent combinations is to elute the lipids based on their polarity to binding of the silica gel. The chromatography is performed on a silica gel plate and the use of iodine to visualize the lipids. By calculating the Rf values for each compound and comparing them to the known lipids, we are able to distinguish the lipids within the grounded nutmeg.
After this compound is formed, then comes the polymerisation stage1. In the polymerisation stage the compound that is produced is heated at a temperature of 260oC and at a low pressure1. A catalyst is required at this stage to speed up the reaction - there are many options for catalysts such as antimony (iii) oxide1. After this step the polyester is formed and half of the ethane1,2- diol is restored which is removed1.
This clearly shows that the fruits and vegetables play a vital role in maintaining our good health. Fruits and vegetables are seasonal and grown in different parts of our country. They need to be stored for longer period and transported to different places. It makes necessary for us to find out whether there is any damage to the useful contents of the fruits and vegetable during the storage and transportation or due to some preservatives or other factors and what kind of nutrients, minerals, etc. are present in their juices. With this idea in mind, the project has been undertaken.