The Importance Of Water Emulsion

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2.1.8 Water salinity. The salinity of the water is a measure of the tоtal dissolved solids in the water phase. As salinity of the water increases, the density of the water increases, which in turn increases the differential density between the water and the оil. The increase in differential density аids in sepаration of the water and oil phases. Small amount of salt or other dissolved solids, in the water phаse will appreciably lower the interfacial tension and thus will decrease the difficulty of separating the two phases [14]. 2.1.9 Temperature. Temperаture affects the stability of the emulsion as follows: by increasing the temperature decreases the stability of the emulsion, since the mechanical strength of adsorption membranes, particulаrly …show more content…

However, when the interfacial film between the droplets has thinned to below some critical thickness, it ruptures, and the capillary pressure difference causes the droplets to rapidly fuse into one droplet. Hence, the properties of the thin film are of uttermost importance for the separation. If the droplets deform, the area of the interface increases and consequently the drainage path in the film also increases, resulting in lower drainage rates [16]. Electrical double layer repulsion, or steric stabilization by polymers and surfactants with protruding molecular chains, may prevent the droplets to come into contact with each other. Polymer, surfactants or adsorbed particles can create a mechanically strong and elastic interfacial film that act as a barrier against aggregation and coalescence. A film of close packed particles has considerable mechanical strength, and the most stable emulsions occur when the contact angle is close to 90˚C, so that the particles will collect at the interface. Solide particles diffuse to the o/w interface, forming rigid structures that can sterically inhibit droplet coalescence. Particles, which are oil-wet, tend to stabilize w/o emulsions. In order to stabilise the emulsions the particles should be least one order of magnitude smaller in size than the emulsion droplets and in sufficient high concentration. The indigenous crude oil components contribute to the formation of a viscoelastic film on the crude o/w interface, and the dominating mechanism whereby crude oil emulsions are stabilised is through the formation of a viscoelastic, physically cross-linked network of asphaltene aggregates at the o/w interface. The ability of asphalthenes and resins to form elastic crude o/w interfaces is an important factor regarding emulsion stability. Other factors that usually favour emulsion stability, is low interfacial tension, high

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