Chemistry: Condensation Of Polymers

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Name: Mayedah Kirmani Group: 5 Instructor: Dr. Tayyaba Noor Course: Organic and Biochemistry (CH-202) Date of submission: 1st December 2015. Condensation of Polymers Condensation polymers are kinds of polymers made through a condensation reaction where the molecules link together eliminating small molecules as by-products such as water or methanol, contrasting to addition polymers which comprise of the reaction of unsaturated monomers. Monomers The monomers that take part in condensation polymerization are not similar to the ones that are involved in addition polymerisation. Theses monomers for condensation polymerization have two attributes: • Instead of double bonds, these monomers have functional groups like alcohol, amine or carboxylic …show more content…

He wanted to discover a material that would have a high melting point characteristic and also be impervious to oxidation which eventually directed him to form Poly (ether-ether-ketone) PEEK is a polymer which can withstand very high temperatures; boiling water pans are made out of this and also cone of missiles. • Polyhydroxyamine This is a polymer which is, if, treated with strong heat, turns into a fire-resistant polymer. On burning no smoke is formed, which makes it convenient as a plastic for aeroplane interiors. When PHA is intensely heated, it loses water and re-arranges to form PBO. PHA is used as a plastic as it is easier to mould so it is used instead of PBO. The Mechanism of Condensation Polymerization Monomers that are combined by condensation polymerization have two functional groups. A carboxylic acid and an amine can form an amide linkage, and a carboxylic acid and an alcohol can construct an ester linkage. So as each monomer has two reactive sites, they can form long chain polymers by making multiple amide or ester links and releasing a small molecule. Examples of the mentioned mechanism are illustrated below. Example

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